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Radical reactions with the participation of selenium compounds have been described here in the point of view of the source of selenium radicals. Consequently, the following groups have been reviewed: alkyl phenyl selenides, acyl phenyl selenides, imidoyl phenyl selenides, benzeneselenol and other selenides as the source of radicals.
The chapter covers the literature from early 90s until 2012.
Keywords: Radicals, Selenides, Stannanes, Silanes, Diselenides, Addition, Cyclization, Coupling, Stereoselectivity, Regioselectivity.
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