Application of Adsorbents for Water Pollution Control

Author(s): Aoife M. Burke, Colm McManamon, Paul Delaney, John P. Hanrahan, Justin D. Holmes and Michael A. Morris

DOI: 10.2174/978160805269111201010238

Mesoporous Silicates for Mitigation of Metal-Ion and Phosphate Pollution in Water

Pp: 238-271 (34)

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Abstract

SHS investigation development is considered from the geographical and historical viewpoint. 3 stages are described. Within Stage 1 the work was carried out in the Department of the Institute of Chemical Physics in Chernogolovka where the scientific discovery had been made. At Stage 2 the interest to SHS arose in different cities and towns of the former USSR. Within Stage 3 SHS entered the international scene. Now SHS processes and products are being studied in more than 50 countries.

Abstract

In this chapter, the development of novel, highly ordered, mesoporous materials, which can be used to provide active sorbents for mitigation of environmental pollutants, has been discussed. Specifically, focus was given on the use of these materials for water pollution remediation through the extraction of metal ions and phosphate ions (as these are the most important pollution problems in industrialised regions). Also, a review is presented on some of the recent works in this field including some of our most recent studies. A variety of porous materials were synthesised including mesoporous particles and macroporous spheres and these were characterised using powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and nitrogen adsorption techniques to establish the pore diameters, material morphology, packing of the pores and specific surface areas of the materials. Pure silica materials have limited efficacy in these applications and it was necessary to modify their properties with a selection of ligands and metal ion dopants to tailor their sorptive properties towards the selected applications. The extraction efficiencies of each sorbent was quantified using a number of analytical procedures depending on the nature of the pollutant studied.

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