Multifunctional Two- and Three-Dimensional Polycrystalline X-Ray Diffractometry

Author(s): Cong Qiuzi, Yu Xiang and He Li

DOI: 10.2174/978160805076511101010017

Bragg’s Law and Multifunctional 2D X-Ray Diffractometry

Pp: 17-33 (17)

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Abstract

SHS investigation development is considered from the geographical and historical viewpoint. 3 stages are described. Within Stage 1 the work was carried out in the Department of the Institute of Chemical Physics in Chernogolovka where the scientific discovery had been made. At Stage 2 the interest to SHS arose in different cities and towns of the former USSR. Within Stage 3 SHS entered the international scene. Now SHS processes and products are being studied in more than 50 countries.

Abstract

INTRODUCTION

New concept of X-ray crystalline diffractometry is presented to interpret the functions of X-ray diffraction equipment, such as the Bragg-Brentano diffractometer, Seemann-Bohlin camera (or diffractometer), and Debye back-and transmission-cameras, etc. Bragg’s law, as the fundamental theory in X-ray analysis, is suitable to interpret all the phenomena of X-ray diffraction. However, relative orientations of crystal planes observed in respect to the sample surface, which is potentially of great interest from a purely scientific and from an applicative point of view, cannot be shown by the commercial equipment itself, the term “azimuth relationship” is therefore introduced here.

The concept of two-dimension (2D) diffraction in its many aspects is important in X-ray geometric optics. Now, both Bragg’s and azimuth-angle equations are used to outline the configuration and arrangements of the X-ray equipment as a quaternity figure shown in Fig. 1 at present describing features of the multifunctional 2D/3D X-ray diffractometry.

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