The Synthetic Methods, Structures, and Properties of the Ca-C σ Bond Organocalcium Containing Compounds

Author(s): Nejib Ben Hussein Mekni and Noureddine Raouafi

DOI: 10.2174/9789815040647122010004

Calcium Element

Pp: 3-19 (17)

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Abstract

SHS investigation development is considered from the geographical and historical viewpoint. 3 stages are described. Within Stage 1 the work was carried out in the Department of the Institute of Chemical Physics in Chernogolovka where the scientific discovery had been made. At Stage 2 the interest to SHS arose in different cities and towns of the former USSR. Within Stage 3 SHS entered the international scene. Now SHS processes and products are being studied in more than 50 countries.

Abstract

In this second chapter, we have grouped the physical and chemical properties of elemental calcium and calcium cation species as well as their importance in the human body, especially in the skeleton and cell, as well as their applications in the chemical, electrical, and biological life fields. In a nutshell, we describe the history of the organocalcium Ca-Cσ-bond containing compounds. Then, we expose the encountered challenges and difficulties in the synthesis of organocalcium Ca-C containing compounds: before, during and after the organocalcium preparation and the solutions to overcome these difficulties. We have grouped the calcium activation methods, the nature of the solvent, the substrate structure, temperature and the optimal experimental reaction conditions. 

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