Advances in Organic Synthesis

Author(s): Haydar Göksu * .

DOI: 10.2174/9789815040524122170004

Stereoselective Procedures for the Synthesis of Olefines

Pp: 53-100 (48)

Buy Chapters

* (Excluding Mailing and Handling)

  • * (Excluding Mailing and Handling)

Abstract

SHS investigation development is considered from the geographical and historical viewpoint. 3 stages are described. Within Stage 1 the work was carried out in the Department of the Institute of Chemical Physics in Chernogolovka where the scientific discovery had been made. At Stage 2 the interest to SHS arose in different cities and towns of the former USSR. Within Stage 3 SHS entered the international scene. Now SHS processes and products are being studied in more than 50 countries.

Abstract

Olefins are molecules containing double bonds and are an active functional class. They have the potential to react easily due to the pi bonds in their structures. Therefore, olefins themselves form a biologically active class. In addition, they are pioneer molecules in obtaining different derivatives over many reaction types in organic chemistry. The presence of double bonds brings along geometric isomers (e.g., cis, trans, E, Z). The biological activities of olefins differ in geometric isomers. Therefore, stereoselectivity is important for the synthesis of olefins. In stereoselective olefin synthesis, the control is in the hands of the synthetic organic chemist. Stereoselectivity can be controlled with a correct and practical method. In this study, i) geometric isomers ii) biological activities and iii) stereoselective synthesis of olefins are focused. 

We recommend

Favorable 70-S: Investigation Branching Arrow

Authors:Bentham Science Books