Combustion Synthesis: Novel Routes to Novel Materials

Author(s): Slavko Mentus

DOI: 10.2174/978160805155711001010055

Gel-Combustion Synthesis

Pp: 55-71 (17)

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Abstract

SHS investigation development is considered from the geographical and historical viewpoint. 3 stages are described. Within Stage 1 the work was carried out in the Department of the Institute of Chemical Physics in Chernogolovka where the scientific discovery had been made. At Stage 2 the interest to SHS arose in different cities and towns of the former USSR. Within Stage 3 SHS entered the international scene. Now SHS processes and products are being studied in more than 50 countries.

Abstract

Recently gel combustion synthesis was widely used to synthesize various forms of simple or complex metal oxides, having a wide range of applications. The chapter, after introductory remarks, begins with the ways of preparation of gelled oxide precursors, their physicochemical characteristics and their ability to burn in terms of chemical composition. Then follows a survey of the synthesis of various ceramics materials (electronic superconductors, ionic conductors, dielectrics, ferroelectrics), catalysts (non-supported and supported) electrode materials for chemical power sources (anode and cathode materials for ion-lithium cells), in a powdery form. Finally, the methods to transform the powdery gel combustion products to other valuable materials, for example to bulk oxide materials, or to films and powders of metals and alloys, will be described.

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