Liquid Crystal Light Modulators: Revised Edition

Author(s): Przemysław Kula

DOI: 10.2174/9789811470226120010007

Nematic Mixtures for Liquid Crystal Light Modulators

Pp: 31-67 (37)

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Abstract

SHS investigation development is considered from the geographical and historical viewpoint. 3 stages are described. Within Stage 1 the work was carried out in the Department of the Institute of Chemical Physics in Chernogolovka where the scientific discovery had been made. At Stage 2 the interest to SHS arose in different cities and towns of the former USSR. Within Stage 3 SHS entered the international scene. Now SHS processes and products are being studied in more than 50 countries.

Abstract

In the last few years, the following Multicomponent Nematic Liquid Crystalline (MNLC) mixtures of medium and high optical anisotropy Δn have been developed in Military University of Technology (MUT) in Warsaw:

• W1898 (composed mainly of two and three alkylcyclohexylbenzene and alkylbicyclo-hexylbenzene isothiocyanates),

• W1820 (composed mainly of fluoro-substituted alkylbiphenylisothiocyanates),

• W1852 (composed mainly of fluoro-substituted isothiocyanates, alkylbiphenyls, alkylcyclo-hexylbiphenyls and alkylbicycloheksylobiphenyls),

• W1825 and W1791 (composed mainly of fluoro-substituted isothiocyanates, alkyltolanes and alkylphenyltolanes),

• W1865 (composed mainly of fluoro-substituted isothiocyanates, alkylphenyls and alkylbiphenyltolanes),

• W1115 (composed mainly of cyclohexanolcyanobenzenes, fluorobenzenes and hydrocarbons),

• W1795B (composed mainly of fluoro-terphenyls).

In this chapter, the material characteristics of the perpendicular and parallel εII(T) components of the permittivity tensors ε (T) at the frequency range of f є [10 Hz, 10 MHz]; bulk viscosity Γ(T); rotational viscosity γ(T), splay K11(T), twist K22(T), bend K33(T) and KTN(T) for transition from twisted to the nontwisted structure; ordinary no(λ) and extraordinary ne(λ) refractive indices for wavelength λ є [0.3μm, 1.6 μm] are described and discussed in the terms of applicability of MNLCs to Liquid Crystal electro-optical Devices (LCEOD).

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