Advances in Organic Synthesis

Author(s): Yu Lin Hu

DOI: 10.2174/9781681086958118090004

Recent Advances in Catalytic Organic Synthesis Applications of Covalently Supported Ionic Liquids

Pp: 25-71 (47)

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Abstract

SHS investigation development is considered from the geographical and historical viewpoint. 3 stages are described. Within Stage 1 the work was carried out in the Department of the Institute of Chemical Physics in Chernogolovka where the scientific discovery had been made. At Stage 2 the interest to SHS arose in different cities and towns of the former USSR. Within Stage 3 SHS entered the international scene. Now SHS processes and products are being studied in more than 50 countries.

Abstract

Supported ionic liquids have attracted increasing attentions in the area of organic synthesis due to their significant properties including good chemical and thermal stability, wide liquid temperature range, considerable ionic conductivity, nonflammability, and high surface area with a remarkable level of catalytic performance. Moreover, due to their heterogeneous properties, they have the attractive features of easy separation and recyclability. This review covers recent studies on the applications of supported ILs as green catalysts for the traditional reagents in catalytic organic synthesis such as condensation reaction, oxidation, coupling reactions as well as some other reactions. The adaptabilities of supported ILs in these reactions are predicted as a solution to the problems of conventional chemical processes and to become a powerful method in organic synthesis.

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