The second law of thermodynamics is an example of the fundamental laws that govern our universe and is relevant to every branch of science exploring the physical world. This reference summarizes knowledge and concepts about the second law of thermodynamics and entropy. A verbatim explanation of chemical thermodynamics is presented by the author, making this text easy to understand for chemistry students, researchers, non-experts, and educators.

This eBook covers the application of high-throughput R&D to both fundamental and applied catalysis including catalyst synthesis, characterization, and testing in various reactor types. Chapters include topics such as applications ranging from optimizations of established industrial catalysts to the discovery of innovative new materials, examples of the development of innovative parallel characterization methods, and cases of real catalyst testing in small scale reactor systems. Readers will also find chapters that cover commodity chemicals produced using continuous gas phase processes as well as fine chemicals produced in liquid phase batch reactors. The potential of industrial chemicals production from biorenewable feedstocks is also presented. The steadily improving high throughput workflows are today being applied to relevant reactions and targets such as hydrotreating, Deacon oxidation, Fischer-Tropsch, propane dehydrogenation, C4 oxidation, methane coupling, exhaust gas catalysis, bio-based Nylon, fuel cells and vitamins. The topics presented in this eBook have been contributed by researchers from academia as well as industry, making this eBook a well-balanced reference, which could be of particular interest to professional, industrial or service R&D labs.

Understanding the dispersion and the deposition of inertial particles convected by turbulent flows is a domain of research of considerable industrial interest. Inertial particle transport and dispersion are encountered in a wide range of flow configurations, whether they are of industrial or environmental character. Conventional models for turbulent dispersed flows do not appear capable of meeting the growing needs of chemical, mechanical and petroleum industries in this regard and physical environment testing is prohibitive. Direct Numerical Simulation (DNS) and Large Eddy Simulation (LES) have become powerful tools for the investigation of particle-laden turbulent flows with the help of advances in computing resources. The hybrid Eulerian-Lagrangian approach plays a key role in predicting inertial particle dispersion and deposition. This ebook explains the use of stochastic tools to enhance the accuracy of the Eulerian-Lagrangian large eddy simulation of particle-laden turbulent flows of practical interest. The book should be a useful resource for chemical, mechanical, petroleum and environmental engineering postgraduates and researchers interested in applying tractable yet powerful numerical tools to solve problems involving multiphase flows.

This reference provides collective information about the physical and photophysical changes of supramolecules after encapsulation. It covers luminescent systems involving a range of host molecules such as calixarenes, cyclodextrin, resorcinanene-crowns, pillararenes, cucurbituril, and metallacycles. Chapters also discuss the effect of the macrocyclic environment on the properties of functionalized molecules, including the variations in folding and unfolding patterns. Each chapter is supplemented with detailed references, making this an ideal resource for scholars interested in supramolecular photophysics.