Current Organic Chemistry

Author(s): Regine Fuchs and Herbert Budzikiewicz

DOI: 10.2174/1385272013375562

DownloadDownload PDF Flyer Cite As
Structural Studies of Pyoverdins by Mass Spectrometry

Page: [265 - 288] Pages: 24

  • * (Excluding Mailing and Handling)

Abstract

The siderophores produced by the so-called fluorescent members of the bacterial genus Pseudomonas called pyoverdins are chromopeptides with complex structures. Their peptidic part - linear or partially cyclic - comprises unusual and partially modified amino acids. So far about fifty different pyoverdines have been encountered. A fast establishing at least of their gross structure is of importance for the identification of strains in medicine, agriculture and in waste degradation. Mass spectrometric techniques have become a potent tool in this respect. Results which have been obtained by the various techniques will be reviewed.

Keywords: Pyoverdins by Mass Spectrometry, siderophore, Pseudomonas, Ferribactins, Fast Atom Bombardment FAB, Electron, Chemical Ionzation, Isopyoverdins, Retro-Diels-Alder, Ion trap CA spectrum