Abstract
Introduction: The synthesis of copper soap (laurate), and its complex with 2-amino 6-
methylbenzothiazole and their elemental and spectral analysis have been done for comparative studies
using IR, NMR, Mass and ESR spectra.
Methods: The fungicidal activities, with reference to Alternaria alternata and Aspergillus niger at
different concentrations by P.D.A. technique were also studied.
Results and Conclusion: The present research work comprises detailed thermal analysis using
TGA technique to determine their kinetic and thermodynamic parameters by applying various
equations like Freeman Carroll, Coats-Redfern equation, Horowitz-Metzger equation, Broido
equation, Piloyan–Novikova equation.
Keywords:
Copper surfactants, 2-amino 6- methylbenzothiazole, anti-fungal studies, lauric acid, thermodynamic parameters,
horowitz-metzger.
Graphical Abstract
[1]
Joram, A.; Sharma, R.; Sharma, A.K. Spectral & TGA Studies of Cu Soaps of various oils & Their Complexes LAP Lambert Academic Publishing; Germany, 2017.
[6]
Bakr, F.A.W.; Mohamed, H.N.; Awad, G.A.E. Synthesis and biological activity of some new 1,2,3- triazole hydrazone derivatives. Eur. Chem. Bull., 2015, 4(2), 106-109.
[10]
Sharma, A.K.; Sharma, R.; Gangwal, A. Comparative critical micellar concentration parameters of biopotent metal - benzothiazole chelates in different chemical compositions. Curr. Phys. Chem., 2018, 8(4), 253-262.
[11]
Garg, B.S.; Kumar, D.N. Spectral studies of complexes of nickel (II) with tetradentateschiff bases having N2O2 donor groups. Spectrochim. Acta, 2003, 59A, 229-234.
[13]
Sharma, A.K.; Saxena, M.; Sharma, R. Ultrasonic studies of copper soaps urea complexes derived from mustard and soyabean oils. J. Phy. Sciences (New York), 2018, 29(3), 67-82.
[16]
Khan, S.; Sharma, R.; Sharma, A.K. Acoustic studies and other acoustic parameters of Cu(II) Soap derived from nonedible neem oil (Azadirectaindica), Non-aqueous media at 298.15. Acta Acustica united with Acustica, 2018, 104, 277-283.
[17]
Mehrotra, K.N.; Varma, R.P. Studies on surface tension of the system: barium soap-water and propanol-1. J. Am. Chem. Soc., 1969, 46(3), 152-154.
[20]
Mehrotra, K.N.; Varma, R.P. Studies on the physical proper-ties of the system: barium caproate*-water and propanol-1. J. Am. Oil Chem. Soc., 1969, 46, 568-592.
[27]
Bhutra, R. Sharma, R.; and Sharma, A.K. Fungicidal activities of Cu (II) soaps derived from various oils treated at high temperature for biomedical use. SAJ Biotechnol., 2018, 5, 1-6.
[29]
Joram, A.; Sharma, R.; Sharma, A.K. Thermal degradation of complexes derived from Cu (II) groundnut soap (Arachishypogaea) and Cu (II) sesame soap (Sesamumindicum). Z. Phys. Chem. (N F), 2018, 232(4), 459-470.