Fullerene-like Nanoparticles of WS2 as a Promising Protection from Erosive Wear of Gun Bore Nozzles

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Abstract

Background: Erosive wear causes increase in the bore diameter of firearms barrels and nozzles. Most responsible factors for this erosion are friction and heat generated during the shot. Protection from erosive wear is very important for gun tube life cycle, and various protection methods are used: adding phlegmatizers in gunpowder composition or applying protective layers on the gun bore inner surface.

Objective: In this research, a possibility is examined to protect the surface of a nozzle exposed to gunpowder erosion applying a layer of tungsten disulfide fullerene-like nanoparticles, IF-WS2, known as outstanding solid lubricant of a great mechanical resistance.

Methods: Nanoparticles on the nozzle surface before and after the gunfire tests were observed using scanning electron microscopy/energy dispersive X-ray spectroscopy. Gunfire tests were performed on designed erosion device. Temperatures in the defined position near the affected surface were measured with thermocouples and compared for the nozzles with and without nanoprotection, as well as the nozzle mass loss after each round.

Results: For the sample with IF-WS2 lower temperatures after firing and lower mass losses were observed. Mass loss after first round was 25.6% lower for the sample with protective nanoparticles layer, and the total mass loss was about 5% lower after five rounds. After the first round the nozzle without IF-WS2 was heated up to a temperature which was for 150.8°C higher than the nozzle with IF-WS2.

Conclusion: Protective function of IF-WS2 is the most pronounced for the first round. The observed results encourage its further application in firearms gun bores protection.

Keywords: Nanoparticles, inorganic fullerenes, erosion, wear resistance, solid lubrication, firearms.

Graphical Abstract

[1]
Niklas, L.B.; Tim, M.S.T.; Daniéla, Q.; Filip, S.L. Self-Lubricating Components, 1st ed; Uppsala Universitet: Uppsala, 2017.
[2]
Rapoport, L.; Bilik, Y.; Feldman, Y.; Homyonfer, M.; Cohen, S.R.; Tenne, R. Hollow nanoparticles of WS2 as potential solid-state lubricants. Nature, 1997, 387, 791-793.
[3]
Tevet, O. Mechanical and Tribological Properties of Inorganic Fullerene-Like (IF) Nanoparticles. PhD Thesis, Weizmann Institute of science: Rehovot, 2011.
[4]
Rapoport, L.; Bilik, Y.; Feldman, Y.; Homyonfer, M.; Cohen, H.; Sloan, J.; Hutchison, J.L.; Tenne, R. Inorganic fullerene-like material as additives to lubricants: Structure–function relationship. Wear, 1999, 225-229, 975-982.
[5]
Simić, D.; Dušica, B.; Stojanović, A.K.; Dimić, M.; Totovski, L.; Petar, S.; Uskoković, R.A. Inorganic fullerene-like IF-WS2/PVB nanocomposites of improved thermo-mechanical and tribological properties. Mater. Chem. Phys., 2016, 184, 335-344.
[6]
Lazić, D.S.; Simić, D.; Samolov, A.D.; Jovanović, D. Properties of standard polymeric and water-based coatings for military camouflage protection with addition of inorganic fulerene-like tungsten disulphide (IF-WS2) nanoparticles. Sci. Technol. Rev., 2017, 67, 38-44.
[7]
Chate, P.A.; Sathe, D.J.; Hankare, P.P. Electrical, optical and morphological properties of chemically deposited nanostructured tungsten disulfide thin films. Appl. Nanosci., 2013, 3, 19-23.
[8]
Ankush, R.; Ankush, A. Efect of nanodiamond on friction and wear behavior of metal dichalcogenides in synthetic oil. Appl. Nanosci., 2018, 8, 581-591.
[9]
Guo, R.; Jiao, T.; Li, R.; Chen, Y.; Guo, W.; Zhang, L.; Zhou, J.; Zhang, Q.; Peng, Q. Sandwiched Fe3O4/carboxylate graphene oxide nanostructures constructed by layer-by-layer assembly for highly efficient and magnetically recyclable dye removal. ACS Sustain. Chem. Eng., 2018, 6, 1279-1288.
[10]
Liu, Y.; Hou, C.; Jiao, T.; Song, J.; Zhang, X.; Xing, R.; Zhou, J.; Zhang, L.; Peng, Q. Self-assembled AgNP-containing nanocomposites constructed by electrospinning as efficient dye photocatalyst materials for wastewater treatment. Nanomaterials, 2018, 8, pii: 35.
[11]
Chen, K.; Li, J.; Zhang, L.; Xing, R.; Jiao, T.; Gao, R.; Peng, Q. Facile synthesis of self-assembled carbon nanotubes/dye composite films for sensitive electrochemical determination of Cd(II) ions. Nanotechnology, 2018, 29 445603
[12]
Luo, X.; Ma, K.; Jiao, T.; Xing, R.; Zhang, L.; Zhou, J.; Li, B. Graphene oxide-polymer composite langmuir films constructed by interfacial thiol-ene photopolymerization. Nanoscale Res. Lett., 2017, 12, 99.
[13]
Sliney, H.E. Solid lubricant materials for high temperatures - A review. Tribol. Int., 1982, 15, 303-315.
[14]
Roberts, E.W. Thin solid lubricant films in space. Tribol. Int., 1990, 93, 95-104.
[15]
Vivek, T.R.; Jayanth, S.K.; Anjana, J. Polymer and ceramic nanocomposites for aerospace applications. Appl. Nanosci., 2017, 7, 519-548.
[16]
Nanotech Industrial Solutions. Space and Defense. Available from:. https://nisusacorp.com/applications/space-and-defense (Accessed on: August 25, 2018).
[17]
Erčević, M.; Petrović, V.; Luković, B. Applying of nanotechnology in production of rifle ammunition. Proceedings of the 7th International Conference on Defensive Technologies OTEH, Belgrade Serbia, October 6-7,2016, pp. 260-265.
[18]
Boban, G. Tribological Comparison of Traditional and Advanced Firearm Coatings.. Master thesis, Faculty of California Polytechnic State University: San Luis Obispo, June, 2010.
[19]
Rapoport, L.; Nepomnyashchy, O.; Lapsker, I.; Verdyan, A.; Moshkovich, A.; Feldman, Y.; Tenne, R. Behavior of fullerene-like WS2 nanoparticles under severe contact conditions. Wear, 2005, 259, 703-707.
[20]
Lawton, B. Thermo-chemical erosion in gun barrels. Wear, 2001, 251, 827-838.
[21]
Chung, D.; Shin, N.; Oh, M.; Yoo, S.; Nam, S. Prediction of erosion from heat transfer measurements of 40mm gun tubes. Wear, 2007, 263, 246-250.
[22]
Johnston, I. Understanding and Prediction Gun barrel Erosion. Technical rept. ADA 440938, Weapons Systems Division, Defence Science and Technology Organisation Edinburgh, Australia, 2005.
[23]
Lawton, B. Thermal and chemical effects on gun barrel wear Proceedings of the 8th International Symposium of Ballistics, Orlando, USA 23-25 October1984.
[24]
Ebihara, W.T.; Rorabaugh, D.T. Mechanisms of gun-tube erosion and wear. In Gun Propulsion Technology. Vol. 109 of Progress in Astronautics and Aeronautics; Stiefel, L., Ed.; AIAA: Washington, D.C., 1988, Chapter 11,, pp. 357-376.
[25]
Sopok, S.; Rickard, C.; Dunn, S. Thermal-chemical-mechanical gun bore erosion of an advanced system, part one: Theories and mechanisms. Wear, 2005, 258, 659-670.
[26]
Finnie, I.; McFadden, D.H. On the velocity dependence of the erosion of ductile materials by solid particles of low angles of incidence. Wear, 1978, 48, 36-58.
[27]
Adžić, M.; Heitor, M.V.; Santos, D. Design of dedicated instruments for temperature distribution measurements in solid oxide fuel cells. J. Appl. Chem, 1997, 27, 1355-1361.
[28]
Adžić, M. Determination of inner surface gun bore temperature. (in Serbian) Sci. Technol. Rev., 1997, 45, 70-73.
[29]
Jaramaz, S.; Micković, D.; Elek, P. Determination of gun propellants erosivity: Experimental and theoretical studies. Exp. Therm. Fluid Sci., 2010, 34, 760-765.
[30]
Carasso, A. Determining surface temperatures from interior observations. SIAM J. Appl. Math., 1982, 42, 558-574.
[31]
Carasso, A. Nonlinear Inverse Heat Transfer Calculations in Gun Barrels. Report ARO 19643.1-MA, Center for Applied Mathematics, National Bureau of Standards, Washington, 1983.