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Letters in Organic Chemistry

Author(s): Mohammad Javad Taghizadeh*, Huoman Karimi and Akbar Mirzaie

DOI: 10.2174/1570178615666180622123944

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Zeolite-encapsulated Mn(II) Complex: A New Nano Catalyst for the Synthesis of Modafinil and Its Derivatives

Page: [541 - 549] Pages: 9

  • * (Excluding Mailing and Handling)

Abstract

The Mn-hydrazone Schiff base encapsulated into NaY has been prepared and characterized as a new heterogeneous catalyst. Elemental analysis, UV-Vis, infrared spectroscopic analysis, diffused reflectance spectroscopy, thermal analysis, small angle X-ray diffraction, and N2 sorption demonstrate the existence of Mn-hydrazone schiff base in the nanopores of zeolite-Y. MnII(Hsal- hrz)/Y, which showed excellent catalytic property in oxidation with various sulfide compounds including important drugs such as adrafinil and modafinil, using hydroperoxide-urea (UHP) as oxidant. Thioanisole conversion was high (98%).

Keywords: Heterogeneous catalyst, sulfoxidation, adrafinil, modafinil, zeotite, hydrazone.

Graphical Abstract

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