Author(s): Zhu-Qing Wang, Meng-Ping Guo*, Yong-Ju Wen, Xiu-Li Shen, Mei-Yun Lv and Xiu-Ling Zhou
Page: [891 - 894] Pages: 4
* (Excluding Mailing and Handling)
An efficient and novel nitrating reagent has been developed for ipso-nitration of arylboronic acids. By using inexpensive and commercially available Cu(NO3)2/CF3COOH as nitrating reagent, various nitroarenes are produced in moderate to excellent yields (51-96%). Advantages of this procedure are the operational simplicity and no need of extra catalyst.
Keywords: Arylboronic acids, Cu(NO3)2/CF3COOH as nitrating reagent, ipso-Nitration, nitroarenes, catalyst-free.
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