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Current Green Chemistry

Author(s): Yunyun Liu and Weijiang Wen

DOI: 10.2174/2213346102666150702155424

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A Clean and Practical Catalyst free Synthesis of Keto and Aldoximes as well as the Beckmann Rearrangement by using Ethyl Lactate as an Environmentally Benign Medium

Page: [399 - 402] Pages: 4

  • * (Excluding Mailing and Handling)

Abstract

Ethyl lactate, a bio-based nontoxic solvent has been found as a medium for the general synthesis of keto- and aldoximes under catalyst-free conditions. The synthesis of amides via Fe-catalyzed Beckmann rearrangement of the ketoxime has also been realized in the same green medium.

Keywords: Aldoximes, bio-based medium, ethy lactate, ketoximes, sustainable synthesis.