Bismuth Nitrate Catalyzed Microwave Assisted Aza-Diels Alder Reaction for Synthesis of Bicyclo[2,2,2]-Octanones Scaffold

Ram   Naresh   Yadav; Ashwini      Bobbala; Sunena      Chandra; Bimal   K.   Banik

Current Microwave Chemistry

Author(s): Ram Naresh Yadav, Ashwini Bobbala, Sunena Chandra and Bimal K. Banik

DOI: 10.2174/2213335601666140630165348

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Bismuth Nitrate Catalyzed Microwave Assisted Aza-Diels Alder Reaction for Synthesis of Bicyclo[2,2,2]-Octanones Scaffold

Page: [94 - 97] Pages: 4

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Abstract

Bismuth nitrate-catalyzed microwave-assisted one-pot three components Aza-Diels-Alder reaction has been investigated. This method has been used for an efficient synthesis of 2-azabicyclo[2,2,2] cyclooctanones.

Keywords: Alkaloids, aza-Diels-Alder, azabicycle, bismuth nitrate, cycloadducts, diastereoselectivity, dienophile, endo/exo, heterocycles, in situ, keto-enol tautomerization, Lewis acid, microwave chemistry, natural product, one-pot chemistry.

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