Abstract

The asymmetry porphyrin incorporates into mesoporous molecular sieves SBA-15 which through the reaction of the OH group of SBA-15 with the fluorine group of the porphyrin. The resultant material was characterized by means of XRD, TEM, solid UV/Vis, FTIR and nitrogen adsorption. Results indicate that the channels of SBA-15 have been filled with porphyrins. Luminescent property was studied by solid fluorescent emission and excitation spectra. Result indicates that the property of SBA-15/porphyrin is better than that of the pure porphyrin.

Keywords: Assembly, Asymmetry porphyrin, Characterized, Hydrogen bond, Luminescent property, Mesoporous, Mesoporous material, Metal complex, SBA-15, Synthesis.