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Letters in Organic Chemistry

Author(s): Gowravaram Sabitha, G. Chandrashekhar, D. Vasudeva Reddy and J. S. Yadav

DOI: 10.2174/157017812801264656

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Synthesis of (+)-(4S,5S)-Muricatacin via Pd-Catalyzed Stereospecific Hydroxy Substitution Reaction of γ,δ-epoxy α,β-Unsaturated Ester with B(OH)3

Page: [344 - 346] Pages: 3

  • * (Excluding Mailing and Handling)

Abstract

The stereoselective synthesis of (+)-(4S,5S)-muricatacin has been achieved involving the palladium-catalyzed stereospecific hydroxy substitution reaction of γ,δ-epoxy α,β-unsaturated ester with B(OH)3.

Keywords: γ-Lactone, Pd-catalyzed, γ, δ-epoxy α, β-unsaturated ester, muricatacin, stereospecific, oxidation, pesticidal activities, hydrogenation, palladium