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Letters in Organic Chemistry

Author(s): Francisco A. Marques, Marcos A. Oliveira, Gustavo Frensch, Beatriz Helena L. N. Sales Maia, Andersson Barison, Cesar A. Lenz and Palimecio G. Guerrero

DOI: 10.2174/157017811799304151

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Highly Efficient Kinetic Resolution of Allylic Alcohols with Terminal Double Bond

Page: [696 - 700] Pages: 5

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Abstract

In this study, the lipase-catalyzed kinetic resolution (Novozyme 435) was employed to prepare chiral allylic alcohols and acetates with terminal double bonds in enantiomeric excesses ranging from 94 to > 99 %.

Keywords: Allylic alcohols and acetates, fragrances, pheromones, agrochemicals, high enantiomeric exces, kinetic resolution, Novozyme 435, alcohols, allenols