Generic placeholder image

Letters in Organic Chemistry

Author(s): Pravin V. Shinde, Bapurao B. Shingate and Murlidhar S. Shingare

DOI: 10.2174/157017811797249308

DownloadDownload PDF Flyer Cite As
An Organocatalyzed Expeditious Synthetic Route to Tetrahydrobenzo[a]xanthen-11-ones via Grinding Technique

Page: [568 - 572] Pages: 5

  • * (Excluding Mailing and Handling)

Abstract

In the present study, successful implementation of grinding technique and camphor sulphonic acid (CSA) as a catalyst, has been demonstrated for the rapid synthesis of 12-aryl-9,9-dimethyl-8,9,10,12-tetrahydrobenzo[a]xanthen-11- ones at ambient temperatures, avoiding excessive/wasteful heating.

Keywords: Camphor sulphonic acid (CSA), clean synthesis, green chemistry, grinding technique, solvent-free synthesis, xanthen-11-one derivatives, dodecatungustophosphoric acid, strontium triflate, iodine, ammonium fluoride