Abstract

MgI2 etherate-catalyzed three-component condensation of aldehydes, amines and allyltributylstannane under mild and neutral reaction conditions was developed and efficiently afforded the corresponding homoallylic amine derivatives in good to excellent yields.

Keywords: Aldehydes, allyltributylstannane, homoallylic amines, MgI2 etherate, organometallics, allylpalladiumcomplex, lanthanide, triflates, montmorillonite, Lewis acid