Letters in Organic Chemistry

Author(s): Gopalakrishnapanicker Rajesh Krishnan, Radhakrishnan Sreerekha and Krishnapillai Sreekumar

DOI: 10.2174/157017809787003188

Three Component Mannich Reaction and 1,5-Benzodiazepine Synthesis Catalyzed by a Tetranitrile-Silver Complex

Page: [17 - 21] Pages: 5

  • * (Excluding Mailing and Handling)

Abstract

This manuscript describes the first example of silver ion complex of a dendritic tetranitrile ligand catalyzed one-pot three component Mannich reaction and 1,5-benzodiazepine synthesis. The catalyst can be separated from the products by a change in the solvent. The catalyst is reusable.

Keywords: Homogeneous catalysis, tetranitrile, silver complex, Mannich reaction, 2-aminoketones, 1,5 benzodiazepine