Current Organic Synthesis

Author(s): Ana T. Carmona, Antonio J. Moreno-Vargas and Inmaculada Robina

DOI: 10.2174/157017908784221567

Glycosylation Methods in Oligosaccharide Synthesis. Part 2

Page: [81 - 116] Pages: 36

  • * (Excluding Mailing and Handling)

Abstract

In this part other procedures of glycosylation reactions by direct activation are presented. We will focus on the n-pentenyl glycoside, the O-alkylation and the trichloroacetimidate methods. The use of glycosyl phosphates and glycals in glycosidation reactions are also discussed. Updated examples of these glycosylation methodologies involving total synthesis of oligosaccharides and related compounds are considered.

Keywords: n-pentenyl glycosides, tetrasaccharide, Mycobacterial lipoarabinomannan, bioconjugation, Alkylation