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Letters in Organic Chemistry

Author(s): M.- H. Filippini and J. Rodriguez

DOI: 10.2174/1570178043488716

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From the MARDi Cascade to the Stereoselective Construction of Functionalized Bicyclo[5.4.0]undecene Skeletons Occurring in Natural Compounds

Page: [53 - 54] Pages: 2

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Abstract

The stereoselective construction of functionalized bicyclo[5.4.0]undecene systems, found in many natural sesquiterpenes such as in the widdrane, guadalupane, and recently isolated guanacastepene families, is achieved by selective chemical transformations of a functionalized cycloheptanol arising from the MARDi cascade.

Keywords: mardi cascade, seven-membered rings, bicyclo[5.4.0]undecenes