Generic placeholder image

Letters in Organic Chemistry

Author(s): Mateo Alajarin, Angel Vidal and Fulgencio Tovar

DOI: 10.2174/1570178043400398

DownloadDownload PDF Flyer Cite As
Imino-Ketenimines on an Ortho-Benzylic Scaffold. Nitrogen to Carbon [1,3] Shift of an Ortho-Functionalized Benzyl Group

Page: [340 - 342] Pages: 3

  • * (Excluding Mailing and Handling)

Abstract

Thermolysis of C,C-disubstituted N-(2-benzylideneamino)benzyl ketenimines in solution provided 2,2-disubstituted 3-(2-benzylideneamino)phenylpropionitriles by [1,3] migration of the substituted benzyl group from nitrogen to carbon in the ketenimine fragment.

Keywords: imine, ketenimine, nitrile