Letters in Organic Chemistry

Author(s): Kenneth M. Doll, Randal L. Shogren, Ronald A. Holser, J. L. Willett and Graham Swift

DOI: 10.2174/157017805774717553

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Letters in Organic Chemistry (Polymerization of L-Aspartic Acid to Polysuccinimide and Copoly(Succinimide-Aspartate) in Supercritical Carbon Dioxide)

Page: [687 - 689] Pages: 3

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Abstract

We have prepared two polymeric materials from L-aspartic acid in supercritical carbon dioxide, polysuccinimide and copoly(succinimide-aspartate). The polysuccinimide was characterized by IR spectroscopy and GPC analysis. The copoly(succinimide-aspartate) product was also characterized by titrometric analysis. These natural materials may prove useful in reducing our dependence on petroleum products.

Keywords: Polysuccinimide, copoly(succinimide-aspartate), polyaspartic acid, supercritical carbon dioxide, natural polymer, amino acid polymer