Letters in Organic Chemistry

Author(s): Kamaljit Singh, Amit Sharma, Sonia Behal and Paramjit Kaur

DOI: 10.2174/157017807781212076

Synthesis of meso-Aryl Substituted Porphyrins: Simple and High Yielding Modification of the Adler Procedure

Page: [374 - 377] Pages: 4

  • * (Excluding Mailing and Handling)

Abstract

An efficient single pot route is presented involving the use of O,N-perhydro 1,3-heterocycles as carbonyl equivalents for the synthesis of 5,5-disubstituteddipyrromethanes and meso-tetraarylporphyrins through a high yielding modified Adler route.

Keywords: Oxazinanes, dipyrromethanes, meso-porphyrins, perhydro 1,3-heterocycles, metalloporphyrins, carbonyl equivalents