One-Pot Synthesis of β-Hydroxy-1,3-Dienes Via Allyltriphenylphosphonium Isomerization Under Mild Conditions(SUPPLEMENTARY MATERIAL)

Diver      Sellanes; Laura      Scarone; Eduardo      Manta; Peter      Wipf; Gloria      Serra

Letters in Organic Chemistry

Author(s): Diver Sellanes, Laura Scarone, Eduardo Manta, Peter Wipf and Gloria Serra

DOI: 10.2174/157017806776114621

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One-Pot Synthesis of β-Hydroxy-1,3-Dienes Via Allyltriphenylphosphonium Isomerization Under Mild Conditions(SUPPLEMENTARY MATERIAL)

Page: [309 - 312] Pages: 4

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Abstract

Reaction of allyltriphenylphosphonium bromide and Garners aldehyde in basic media provided β- hydroxy-1,3-dienes. Similar results are described for other aliphatic and aromatic aldehydes.

Keywords: β-hydroxy-1, 3-diene, Garner's aldehyde, Wittig reactions, allyltriphenylphosphonium

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