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Letters in Organic Chemistry

Author(s): Firouz M. Moghaddam, Hamdollah Porkaleh and Hassan Zali-Boeini

DOI: 10.2174/157017806775224314

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Facile Double Fries Rearrangement of Diesters Under Microwave Irradiation; Application to the Synthesis of a Biogenetically Rare Type of Natural Phenol

Page: [123 - 127] Pages: 5

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Abstract

Various diesters successfully undergo a double Fries rearrangement to afford the corresponding bis o-hydroxylaryl ketones, in the presence of AlCl3 under microwave irradiation.

Keywords: Double Fries rearrangement, Microwave irradiation, o-Hydroxyl aryl ketones, Aluminum chloride