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Letters in Organic Chemistry

Author(s): Manef Chtourou*

DOI: 10.2174/1570178620666230727104811

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Base–modified Tunisian Smectite: Efficient Catalysts for Ultrasound- Assisted Knoevenagel Condensation under Mild Reaction Conditions

Page: [66 - 76] Pages: 11

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Abstract

This research work presents the use of base-modified Tunisian Smectite as catalysts for the condensation of Knoevenagel. The prepared clay-catalysts were characterized via FTIR and XRD studies. A series of condensation reactions based on ultrasonic irradiation of various types of active methylene compounds and a variety of aryl aldehydes have shown the high efficacy of prepared catalysts. The stability and catalytic performance of the clay-catalysts were excellent since they could be reused four times without considerable loss in catalytic activity.

Keywords: Base modification, knoevenagel condensation, tunisian smectite, NaOH, LiOH, ultrasound irradiation, aldehydes.

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