Recent Patents on Engineering

Author(s): Mengchen Yuan* and Zhaolong Li

DOI: 10.2174/1872212118666230430004329

Recent Patents of Micro-arc Oxidation Technology

Article ID: e300423216386 Pages: 14

  • * (Excluding Mailing and Handling)

Abstract

Micro-arc oxidation (MAO) is a new surface treatment technology that can improve wear resistance, corrosion resistance, high voltage insulation, and other metal properties. Therefore, this technology is widely used in automobile manufacturing, aerospace, ship anti-corrosion, medical equipment, sewage treatment, and other fields. This paper reviews the representative patents of micro-arc oxidation technology at home and abroad. The micro-arc oxidation processing device, the process method of micro-arc oxidation processing, the power supply and electrical parameters of micro-arc oxidation, the preparation of electrolytes, and the methods of anticorrosion and protection of metal surface are analyzed. The development trend of micro-arc oxidation technology in the future is discussed. Micro-arc oxidation is a simple, green, and environment- friendly surface treatment technology, and there will be more patents in the field of micro- arc oxidation in the future.

Erratum In:
Recent Patents of Micro-arc Oxidation Technology

Graphical Abstract

[1]
T.S.N. Sankara Narayanan, I.S. Park, and M.H. Lee, "Strategies to improve the corrosion resistance of microarc oxidation (MAO) coated magnesium alloys for degradable implants: Prospects and challenges", Prog. Mater. Sci., vol. 60, pp. 1-71, 2014.
[http://dx.doi.org/10.1016/j.pmatsci.2013.08.002]
[2]
Y.K. Pan, D.G. Wang, and C.Z. Chen, "Effect of negative voltage on the microstructure, degradability and in vitro bioactivity of microarc oxidized coatings on ZK60 magnesium alloy", Mater. Lett., vol. 119, pp. 127-130, 2014.
[http://dx.doi.org/10.1016/j.matlet.2013.12.103]
[3]
R.Q. Jia, "Research on micro arc oxidation of magnesium alloys", Mater. Prot., vol. 51, pp. 108-113, 2018.
[4]
S.J. Lee, and L.H.T. Do, "Effects of copper additive on micro-arc oxidation coating of LZ91 magnesium-lithium alloy", Surf. Coat. Tech., vol. 307, pp. 781-789, 2016.
[http://dx.doi.org/10.1016/j.surfcoat.2016.10.008]
[5]
Q. Chen, Z. Jiang, S. Tang, W. Dong, Q. Tong, and W. Li, "Influence of graphene particles on the micro-arc oxidation behaviors of 6063 aluminum alloy and the coating properties", Appl. Surf. Sci., vol. 423, pp. 939-950, 2017.
[http://dx.doi.org/10.1016/j.apsusc.2017.06.202]
[6]
Q. Guo, D. Xu, and W. Yang, "Synthesis, corrosion, and wear resistance of a black microarc oxidation coating on pure titanium", Surf. Coat. Tech., vol. 386, p. 125454, 2019.
[http://dx.doi.org/10.1016/j.surfcoat.2020.125454]
[7]
L. Cui, S. Gao, and P. Li, "Corrosion resistance of a self-healing micro-arc oxidation/polymethyltrimethoxysilane composite coating on magnesium alloy AZ31", Corros. Sci., vol. 118, pp. 84-95, 2017.
[http://dx.doi.org/10.1016/j.corsci.2017.01.025]
[8]
T.H. Qaid, S. Ramesh, F. Yusof, W.J. Basirun, Y.C. Ching, H. Chandran, S. Ramesh, and S. Krishnasamy, "Micro-arc oxidation of bioceramic coatings containing eggshell-derived hydroxyapatite on titanium substrate", Ceram. Int., vol. 45, no. 15, pp. 18371-18381, 2019.
[http://dx.doi.org/10.1016/j.ceramint.2019.06.052]
[9]
Z. Zheng, M.C. Zhao, L. Tan, Y-C. Zhao, B. Xie, D. Yin, K. Yang, and A. Atrens, "Corrosion behavior of a self-sealing coating containing CeO2 particles on pure Mg produced by micro-arc oxidation", Surf. Coat. Tech., vol. 386, p. 125456, 2020.
[http://dx.doi.org/10.1016/j.surfcoat.2020.125456]
[10]
T.G. Ren, X. Gao, and H.Q. Suo, "Research progress in application of micro arc oxidation technology in metal corrosion protection", J. Henan University, vol. 50, no. 3, pp. 305-316, 2020. [Natural Science]
[11]
L. Young, "Space charge in formation of anodic oxide films", Acta Metall., vol. 4, no. 1, pp. 100-101, 1956.
[http://dx.doi.org/10.1016/0001-6160(56)90123-7]
[12]
J. Yahalom, and J. Zahavi, "Electrolytic breakdown crystallization of anodic oxide films on A1, Ta and Ti", Electrochim. Acta, vol. 15, no. 9, pp. 1429-1435, 1970.
[http://dx.doi.org/10.1016/0013-4686(70)80064-0]
[13]
J.J O’DWYER, "The theory of avalanche breakdown in solid dielectrics", J. Phys. Chem. Solids, vol. 18, pp. 1137-1144, 1967.
[14]
J.M. Albella, I. Montero, and J.M. Martinez-Duart, "A theory of avalanche breakdown during anodic oxidation", Electrochim. Acta, vol. 32, no. 2, pp. 255-258, 1987.
[http://dx.doi.org/10.1016/0013-4686(87)85032-6]
[15]
A.K. Vijh, "Sparking voltages and side reactions during anodization of valve metals in terms of electron tunnelling", Corros. Sci., vol. 11, no. 6, pp. 411-417, 1971.
[http://dx.doi.org/10.1016/S0010-938X(71)80125-7]
[16]
J.M. Albella, I. Montero, and J.M. Martínez-Duart, "Electron injection and avalanche during the anodic oxidation of tantalum", J. Electrochem. Soc., vol. 131, no. 5, pp. 1101-1104, 1984.
[http://dx.doi.org/10.1149/1.2115758]
[17]
A. Inoue, and T. Zhang, "“Fabrication of bulky Zr-based glassy alloys by suction casting into copper mold”, Mater. Trans", JIM, vol. 36, no. 9, pp. 1184-1187, 1995.
[http://dx.doi.org/10.2320/matertrans1989.36.1184]
[18]
A.V. Nikoiaev, N.N. Rykaiin, and A.P. Borzhov, "Energy balance of a high current hollow tungsten cathodal", Fizirka i Khimiya Obrabotki Materialov, vol. 2, pp. 32-41, 1977.
[19]
L. Xia, J. Han, J.P. Domblesky, Z. Yang, and W. Li, "Investigation of the scanning microarc oxidation process", Adv. Mater. Sci. Eng., vol. 2017, pp. 1-12, 2017.
[http://dx.doi.org/10.1155/2017/2416821]
[20]
G. Li, J.M. Wang, and L. Shang, "Laser assisted micro-arc oxidation device and processing method", C.N. Patent 20,180,946,6U.
[21]
J.P. Lavoute, P. Brandy, and F. Sansano, "Micro-arc oxidation process manufacturing device", F.R. Patent 3,059,680, A1, 2016.
[22]
Y.B. Chen, M. Liu, and L.M. Cui, "Laser assisted micro-arc oxidation device and processing method", C.N. Patent 11,350,252,3A, 2021.
[23]
X.W. Chen, P.F. Zhao, and D.F. Zhang, "Micro-arc oxidation device for inner wall of titanium alloy pipe and its micro arc oxidation treatment method", C.N. Patent 10,758,718,1A, 2018.
[24]
B.M. Klimenko, T.A. Klimenko, and Y. A. Pechejkina, "Micro-arc oxidation device", R.U. Patent 20,141,254,51A, 2014.
[25]
G.L. Wu, S. Zhang, J.H. Yao, and L. Wang, "A coaxial laser assisted micro-arc oxidation device and method", C.N. Patent 11,389,765,4A, 2021.
[26]
S. Dong, X.H. Liu, and J. Dong, "Micro-arc oxidation device and treatment method", C.N. Patent 11,375,592,1A, 2021.
[27]
G. Chen, J.G. Miao, and Q. Fang, "Hanger for micro-arc oxidation treatment of workpieces with holes", C.N. Patent 21,585,642,4U, 2021.
[28]
G.F. Zhu, N. Wang, and C.B. Wei, "A new high voltage conductive quick loading and unloading hanger", C.N. Patent 11,383,252,6A, 2021.
[29]
G.H. Zhang, "Workpiece hanger for micro-arc oxidation of titanium alloy", C.N. Patent 21,548,135,2U, 2021.
[30]
Y. Niu, J. Jiang, and H.Y. Liu, "A submerged micro-arc oxidation fixture for electrode protection", C.N. Patent 11,368,452,1A, 2021.
[31]
Y. Hu, Z. Wang, J. Ai, S. Bu, and H. Liu, "Preparation of Coating on the Titanium Surface by Micro-Arc Oxidation to Improve Corrosion Resistance", Coatings, vol. 11, no. 2, p. 230, 2021.
[http://dx.doi.org/10.3390/coatings11020230]
[32]
F. Cheng, S. Li, W. Gui, and J. Lin, "Surface modification of Ti-45Al-8.5 Nb alloys by microarc oxidation to improve high-temperature oxidation resistance", Prog. Nat. Sci., vol. 28, no. 3, pp. 386-390, 2018.
[http://dx.doi.org/10.1016/j.pnsc.2018.04.008]
[33]
J.H. Yao, H. Wang, and G.L. Wu, "A method of laser alloying combined with micro-arc oxidation for preparing high temperature oxidation resistant coatings on titanium alloys", C.N. Patent 11,239,162,5A, 2020.
[34]
X.Z. Shi, Y.H. Zhang, and P.M. Chen, "A micro-arc oxidation method for titanium alloy workpieces with low voltage and low current density", C.N. Patent 10,326,633,9A, 2013.
[35]
T. Ouyang, W.Y. Xiang, and Y. Sheng, "Micro-arc oxidation method and titanium alloy structural parts obtained by the method", C.N. Patent 11,090,448,8A, 2019.
[36]
L. Guo, J.T. Hou, and Y. Lu, "A method for preparing high temperature composite coating on titanium alloy surface using micro-arc oxidation solution", C.N. Patent 10,765,347,5A, 2017.
[37]
Y.H. Zhang, X.Z. Shi, and X.H. Liu, "A kind of micro arc oxidation solution, high hardness micro-arc oxidation film of titanium alloy and its preparation and application", C.N. Patent 10,951,825,4A, 2018.
[38]
M. Jiang, "Study on mechanism of micro-arc oxidation film formation of aluminum alloy based on COMSOL", M.S. thesis, Yantai University, Shandong, China, 2018.
[39]
X.J. Yang, Y.Z. Jia, and X.C. Liu, "Micro-arc oxidation process for aluminum alloy", C.N. Patent 10,469,499,0A, 2013.
[40]
P. Guo, "A micro-arc oxidation process for aluminum alloy surface", C.N. Patent 11,189,354,1A, 2020.
[41]
L. Xu, and Q. Bian, "A combined processing method of local mechanical strengthening and micro-arc oxidation on aluminum alloy surface", C.N. Patent 11,191,023,5A, 2020.
[42]
L. Xu, and Q. Bian, "Combined processing method of liquid-solid two-phase flow strengthening and micro-arc oxidation on aluminum alloy surface", C.N. Patent 11,191,023,6A, 2020.
[43]
P.X. Lv, "Micro-arc oxidation ceramic coating on aluminum alloy surface and its preparation method", C.N. Patent 10,408,799,6A, 2014.
[44]
S.K. Wu, W. Yang, and Z.S. Ding, "Micro-arc oxidation layer on the surface of aluminum alloy piston and its preparation method", C.N. Patent 11,276,068,9A, 2011.
[45]
Y. Zhou, Y.M. Jiang, and Z.S. Shao, "A method of improving corrosion resistance of aluminum alloy micro-arc oxidation coating", C.N. Patent 10,240,938,0A, 2020.
[46]
Y. Chen, J. Dou, Z. Pang, H. Yu, C. Chen, and J. Feng, "Improving the corrosion resistance of micro-arc oxidation coated Mg-Zn-Ca alloy", RSC Advances, vol. 10, no. 14, pp. 8244-8254, 2020.
[http://dx.doi.org/10.1039/C9RA10741J] [PMID: 35497822]
[47]
D. Wang, X. Liu, Q. Zhang, Q. Li, H. Chen, Y. Wang, D. Li, and D. Shen, "Investigation on the corrosion resistance of the CuO-Al2O3 composite coating prepared by micro-arc oxidation", Mater. Lett., vol. 288, p. 129396, 2021.
[http://dx.doi.org/10.1016/j.matlet.2021.129396]
[48]
S. Sun, G. Ye, Z. Lu, Y. Weng, G. Ma, and J. Liu, "Surface treatment of Zn-Mn-Mg alloys by micro-arc oxidation in silicate-based solutions with different NaF concentrations", Materials, vol. 14, no. 15, p. 4289, 2021.
[http://dx.doi.org/10.3390/ma14154289] [PMID: 34361481]
[49]
B.L. Jiang, W.T. Sao, X.Y. Zhang, and J. Ma, "A micro-arc oxidation process", C.N. Patent 10,800,457,6A, 2017.
[50]
G.T. Chen, and Y.P. Weng, "A control method of multi cathode time staggered conduction micro-arc oxidation", C.N. Patent 11,006,701,3A, 2019.
[51]
X.P. Lu, X.X. Han, T. Zhang, and F.H. Wang, "Preparation of a self-repairing corrosion resistant micro-arc oxidation coating on alloy", C.N. Patent 10,982,586,6A, 2019.
[52]
M. Wang, "Micro-arc oxidation controllable preparation technology of barium strontium titanate ferroelectric thin films with different Ba2+/Sr2+ ratios", C.N. Patent 10,886,660,0A, 2017.
[53]
W.Z. Li, Z.Q. Chen, and K. Ling, "A SiO2 micro-arc oxidation composite coating and its preparation method", C.N. Patent 10,916,189,0A, 2018.
[54]
D. Chen, and J.M. Li, "Protective coating for ymicro-arc oxidation and its preparation method", C.N. Patent 11,045,259,9A, 2019.
[55]
J.H. Cao, Y.L. Cheng, and H.J. Xie, "A method of micro-arc oxidation on the surface of copper, copper alloy, zinc and zinc alloy", C.N. Patent 10,533,194,1A, 2015.
[56]
R.F. Zhang, D.Y. Shan, R.S. Chen, and E.H. Han, "Effects of electric parameters on properties of anodic coatings formed on magnesium alloys", Mater. Chem. Phys., vol. 107, no. 2-3, pp. 356-363, 2008.
[http://dx.doi.org/10.1016/j.matchemphys.2007.07.027]
[57]
P.N. Wu, J.J. Xi, J. Zhao, and T.J. Wang, "Preparation of compact micro-arc oxidation coatings on aluminum alloys", Appl. Mech. Mater., vol. 33, pp. 492-495, 2010.
[http://dx.doi.org/10.4028/www.scientific.net/AMM.33.492]
[58]
J. Yao, S. Wang, Y. Zhou, and H. Dong, "Effects of the power supply mode and loading parameters on the characteristics of micro-arc oxidation coatings on magnesium alloy", Metals, vol. 10, no. 11, p. 1452, 2020.
[http://dx.doi.org/10.3390/met10111452]
[59]
P. Li, "Study on high-efficiency Three-Phase VSR-ZVZCS power micro-arc oxidation power supply", M.S. thesis, Heilongjiang University of Science and Technology, Heilongjiang, China, 2018.
[60]
J.W. Hou, "Study on bidirectional asymmetric pulse micro-arc oxidation study on bidirectional asymmetric pulse micro-arc oxidation power supply", M.S. thesis, Shenyang University of Technology, Shenyang, China,, 2018.
[61]
D.H. Wei, B. Li, and C.P. Wei, "Micro-arc oxidation power supply device for surface modification of titanium magnesium aluminum", C.N. Patent 21,621,658,9U, 2021.
[62]
Y.P. Guo, Z.G. Wei, X.F. Lu, and X.L. Zhu, "An active oscillation pulsed micro-arc oxidation power supply system and its discharge control method", C.N. Patent 11,389,040,8A, 2021.
[63]
V. Ludin, and E. Andre, "Source current process for processing group parts by micro-arc oxidation", R.U. Patent 165,660, U1, 2015.
[64]
Y. Cheng, T. Wang, S. Li, Y. Cheng, J. Cao, and H. Xie, "The effects of anion deposition and negative pulse on the behaviours of plasma electrolytic oxidation (PEO)-A systematic study of the PEO of a Zirlo alloy in aluminate electrolytes", Electrochim. Acta, vol. 225, pp. 47-68, 2017.
[http://dx.doi.org/10.1016/j.electacta.2016.12.115]
[65]
F.C. Walsh, C.T.J. Low, and R.J.K. Wood, "Plasma electrolytic oxidation (PEO) for production of anodised coatings on lightweight metal (Al, Mg, Ti) alloys", Trans. IMF vol. vol.87, 2009, pp. 122-135, .
[http://dx.doi.org/10.1179/174591908X372482]
[66]
M. Khorasanian, A. Dehghan, M.H. Shariat, M.E. Bahrololoom, and S. Javadpour, "Microstructure and wear resistance of oxide coatings on Ti-Al-4V produced by plasma electrolytic oxidation in an inexpensive electrolyte", Surf. Coat. Tech., vol. 206, no. 6, pp. 1495-1502, 2011.
[http://dx.doi.org/10.1016/j.surfcoat.2011.09.038]
[67]
J.M. Wheeler, C.A. Collier, J.M. Paillard, and J.A. Curran, "Evaluation of micromechanical behaviour of Plasma Electrolytic Oxidation (PEO) coatings on Ti-6Al-4V", Surf. Coat. Tech., vol. 204, no. 21-22, pp. 3399-3409, 2010.
[http://dx.doi.org/10.1016/j.surfcoat.2010.04.006]
[68]
A.L. Yerokhin, X. Nie, A. Leyland, and A. Matthews, "Characterisation of oxide films produced by plasma electrolytic oxidation of a Ti-6Al-4V alloy", Surf. Coat. Tech., vol. 130, no. 2-3, pp. 195-206, 2000.
[http://dx.doi.org/10.1016/S0257-8972(00)00719-2]
[69]
M. Shokouhfar, C. Dehghanian, M. Montazeri, and A. Baradaran, "Preparation of ceramic coating on Ti substrate by plasma electrolytic oxidation in different electrolytes and evaluation of its corrosion resistance: Part II", Appl. Surf. Sci., vol. 258, no. 7, pp. 2416-2423, 2012.
[http://dx.doi.org/10.1016/j.apsusc.2011.10.064]
[70]
Y. Wang, M. Chen, and Y. Zhao, "Preparation and corrosion resistance of microarc oxidation-coated biomedical Mg-Zn-Ca alloy in the silicon-phosphorus-mixed electrolyte", ACS Omega, vol. 4, no. 25, pp. 20937-20947, 2019.
[http://dx.doi.org/10.1021/acsomega.9b01998] [PMID: 31867484]
[71]
F. Simchen, M. Sieber, A. Kopp, and T. Lampke, "Introduction to plasma electrolytic oxidation-an overview of the process and applications", Coatings, vol. 10, no. 7, pp. 628-447, 2020.
[http://dx.doi.org/10.3390/coatings10070628]
[72]
H.X. Li, R.G. Song, J. Zhao, X.H. Zheng, and P. Ye, "Electrolyte and treatment method for preparing nano ceramic coating by micro-arc oxidation", C.N. Patent 10,133,367,3A, 2008.
[73]
Z.Z. Wu, S.P. Ji, and Y.C. Weng, "Electrolyte for micro arc oxidation, micro-arc oxidation method and aluminum or aluminum alloy materials", C.N. Patent 10,683,523,4A, 2017.
[74]
Z.Z. Wu, S.P. Ji, and Y.C. Weng, "Electrolyte for micro arc oxidation, micro-arc oxidation method and its application", C.N. Patent 10,688,419,1A, 2017.
[75]
Y.H. Liu, S. Li, and H.F. Liu, "Electrolyte for surface treatment of magnesium and aluminum alloys by micro-arc oxidation in aluminate system", C.N. Patent 173,721,0A, 2005.
[76]
A.C. Fang, B.L. Jiang, J. Zhao, and H.W. Fang, "An electrolyte suitable for micro-arc oxidation of aluminum and aluminum alloys to prepare ceramic films", C.N. Patent 10,339,736,5A, 2013.
[77]
R.G. Song, "Electrolyte and treatment method for preparing ceramic coating of aluminum alloy by micro-arc oxidation", C.N. Patent 10,531,674,2A, 2014.
[78]
X.L. Xiao, X.C. Chen, M. Kuang, C.G. Deng, and J.F. Zhang, "An electrolyte for preparing aluminum and aluminum alloy ceramic films by micro-arc oxidation", C.N. Patent 10,451,402,7A, 2014.
[79]
Q.J. Zhu, B.B. Wang, B.R. Hou, and X. Zhao, "An electrolyte suitable for micro-arc oxidation of aluminum and aluminum alloys and its application", C.N. Patent 10,793,795,2A, 2017.
[80]
K.Q. Du, X.H. Guo, Z.Q. Guo, and Y. Wang, "A composite nano electrolyte used to prepare micro-arc oxidation film on aluminum alloy surface and its application", C.N. Patent 10,675,726,0A, 2017.
[81]
D.J. Liu, Z.F. Ying, J.W. Zheng, and H.Y. Zhong, "Copper oxide/alumina composite catalyst and its preparation method and special micro-arc oxidation electrolyte", C.N. Patent 10,308,838,7A, 2013.
[82]
R.F. Zhang, A.D. Liao, S.F. Zhang, B. Qu, and L.P. Qiao, "Micro-arc oxidation electrolyte and micro arc oxidation method for titanium alloy", C.N. Patent 10,391,164,4A, 2014.
[83]
W.Q. Wang, Y.D. Li, and M. Qi, "An electrolyte for preparing porous membrane containing bioactive elements on titanium metal surface by micro arc oxidation", C.N. Patent 10,948,732,3A, 2019.
[84]
L.C. Li, "Electrolyte, method and product of micro arc oxidation of titanium alloy", C.N. Patent 11,021,903,4A, 2019.
[85]
L. Wang, F.Y. Shi, and L. Chen, "Micro-arc oxidation electrolyte and its application method, workpiece", C.N. Patent 11,304,681,1A, 2021.
[86]
K. Lv, P.Y. Yan, and Z.C. Feng, "The addition of zirconium carbonate in electrolyte increases the α Wear resistance of micro-arc oxidation film on titanium alloy", C.N. Patent 11,203,021,0A, 2020.
[87]
W.Q. Wang, M. Qin, Y.D. Li, and S.W. Guan, "Electrolyte for preparing porous coating with hierarchical structure on surface of titanium alloy by means of micro-arc oxidation", U.S. Patent 20,210,156,046, 2021.
[88]
M.V. Gerasimov, and N.L. Bogdashkina, "Method for processing titanium and its alloys in order to increase its corrosion resistance and electrolyte for micro-arc oxidation of titanium and its alloys in order to increase corrosion resistance", R.U. Patent 202,110,477,2A, 2021.
[89]
P. Ji, K. Lü, W. Chen, and M. Wang, "Study on preparation of micro-arc oxidation film on TC4 alloy with titanium dioxide colloid in electrolyte", Coatings, vol. 12, no. 8, pp. 1093-1105, 2022.
[http://dx.doi.org/10.3390/coatings12081093]
[90]
Q. Liu, and C. Pu, "Micro-arc oxidation electrolyte and method to reduce brittleness of microporous ceramic film", C.N. Patent 10,827,751,8A, 2018.
[91]
H.X. Li, X. Wu, and R.G. Song, "An electrolyte for micro-arc oxidation self-lubricating composite ceramic coating and its application", C.N. Patent 10,846,807,5A, 2018.
[92]
A.C. Fang, "Micro-arc oxidation electrolyte and micro arc oxidation method", C.N. Patent 11,166,316,2A, 2020.
[93]
R.O. Hussein, X. Nie, and D.O. Northwood, "An investigation of ceramic coating growth mechanisms in Plasma Electrolytic Oxidation (PEO) processing", Electrochim. Acta, vol. 112, pp. 111-119, 2013.
[http://dx.doi.org/10.1016/j.electacta.2013.08.137]
[94]
Z.H. Sun, M. Liu, and D.P. Guo, "Development status and existing problems of micro-arc oxidation technology", Equip. Envir. Eng., vol. 6, no. 6, pp. 46-49, 2019.