[57]
Lin DH, Ke T. In-situ synthesizing titanium dioxide-titanium carbide powder by using dimethyl sulfoxide intercalation and layering of titanium carbide powder comprises e.g. dispersing titanium aluminum carbide-MAX phase ceramic powder, and etching. CN109261180–A, 2018.
[58]
Lin DH, Ke T. Synthesizing titanium oxide-titanium carbide in in situ by isopropylamine intercalation and layering of titanium carbide comprises e.g. dispersing titanium-aluminum carbide-MAX phase ceramic powder in hydrogen fluoride solution and etching CN109261181–A, 2018.
[62]
Su Y, Wang B, Guo XT. et al. BiOBrxI1–x Preparation of /MXene composite catalyst. Patent CN112121833–A, 2020.
[63]
Ren PG, Zhang FD, Guo ZZ, Ren F. Preparation method of CNF/MXene-silver nanowire composite film. Patent CN113004 556-A, 2021.
[64]
Jiang JB, Sun R, Huang X. et al. Synthesis of zinc-doped cobalt phosphide MXene/nickel foam composite material used for electrocatalysis integral water decomposition by etching inorganic salt with titanium aluminum carbide, adding nickel foam into MXene, and reacting. Patent CN114059093-A, 2021.
[65]
Cheng QF, Zhou TZ. Preparing titanium carbide MXene functionalized graphene nanocomposite film in a flexible supercapacitor, involves etching raw material titanium aluminum carbide, using lithium fluoride (LiF) and hydrochloric acid (HCl) as etching agents. Patent CN111252768-B, 2020.
[69]
Barsoum MW, Natu VR. Manufacturing two-dimensional inorganic compound (MXene) material by contacting a metal carbide or nitride (MAX)-phase material with an etchant containing salt, polar solvent and non-polar solvent and crown ether. Patent WO2021076639-A1, 2019.
[70]
Liu HJ, Yang LX, Zeng CL. Preparing laminated MXene material for battery material by directly mixing carbon material powder and second raw material to form multi-element conductive ceramic material, reacting in molten salt, cooling, removing molten salt, and etching. Patent CN110304632-A, 2018.
[76]
Li JL, Zhong JJ, Huo XG, Yang Z. Preparation of MXene anode material used for aluminum ion battery by assembling MAX electrode, high-purity aluminum sheet anode and glass fiber separator in aluminum ion battery, and etching MAX phase to obtain MXene material. CN113381010-A, 2021.
[77]
Chen JZ, Chen MF. Preparing fluorine-free MXene by electrochemical etching method involves taking two MAX respectively as working electrode and counter electrode, soaking in mixed aqueous solution of hydroxide and chloride, and applying voltage, and stirring. CN113461010-A, 2021.
[78]
Hu PF, Liu ZS, Wen HJ, Zhang X, Bian YT, Zhang TX. Preparing MXene by electrochemical etching used as suspension in preparation of composite fiber, involves soaking MAX in absolute ethyl alcohol, performing ultrasonic treatment to remove surface dust, nd drying to prepare electroetching solution, and dispersing MXene in solution. CN114737227-A, 2022.
[99]
Hu MM, Li ZJ, Meng AL. Regulation and control method of twodimensional layered supercapacitor electrode titanium carbide MXene interlayer structure by preparing electrode, placing to sulfate aqueous solution and performing constant-current chargedischarge cycle. CN111029172-A, 2019.
[100]
Wang GG, Zhang SY, Zhao DQ. Preparing porous foam structure MXene-based electromagnetic shielding film comprises preparing MXene dispersion, using hydrogen to cross-link MXene to obtain hydrogen cross-linked processing MXene, compounding hydrogen cross-linked MXene with bacterial cellulose, freezing and casting. CN113881105-A, 2021.
[101]
Tao Y, Wu ZT, Liu XC. et al. Preparing MXene dense porous film with adjustable pore space comprises e.g. preparing MXene microgel dispersion with nano-sheet cross-linked structure from MXene dispersion by cross-linking method, and mixing MXene micro-gel dispersion with MXene dispersion. CN113285070-A, 2021.
[109]
He C L, Ji J J, Liu Z P. MXene silicon-carbon composite material useful in negative electrode, comprises silicon oxide compound base material, nano-carbon coated on surface of silicon oxide base material, and MXene coated on surface of nano-carbon. CN112038641-A, 2020.
[110]
Zhang HT, Huang JF, Sun T. Preparing highly ordered end-group MXene useful in electrode material comprises obtaining MXene etching product, washing, drying, adding MXene powder into dispersion liquid, performing ultrasonic and centrifugation treatments in sequence, collecting upper layer dispersion liquid and plasma etching. CN114843700-A, 2022.
[111]
Huang Q, Li M, Li YB, Luo K, Zhou XB, Du SY. MXene material having a surface group of chlorine useful for preparing electrodes for electrochemical energy storage material, super capacitor material, electromagnetic absorption and shielding material or catalyst. WO2020114196-A1, CN109437177-A, 2018.
[112]
Xu ZH, Lu JM, Hubbard D, Lu ZG. Mxene material grafted with organic chelating functional groups on surface used as capacitive deionization electrode material for removing heavy metal ions in water, is prepared by combining Mxene material and grafting agent comprising amino groups and/or carboxyl groups by siliconoxygen bonds. WO2022165989-A1, CN113003675-A, 2021.
[124]
Huang Q, Ding HM, Li YB. MXene material crystal comprises nitrogen group element end group, where molecular expression of MXene material crystal. CN114395800-A, 2021.
[125]
Koo CM. In IS, Ko TY, et al. Two-dimensional MXene surfacemodified with catechol derivative used as MXene organic ink in electrically conductive film, comprises polyphenol moiety in form of phenyl group containing 2-5 hydroxyl (OH) groups. US2021269664-A1, KR2021103399-A, EP4047062-A1, 2021.
[126]
In IS, Lee JH, Kim SY, Park SM. Surface-modified twodimensional MXene used for e.g. sensor, comprises twodimensional MXene whose outer surface is modified with compound comprising hydroxyl group(s) and/or ionic compound. WO2022107992-A1, KR2022067653-A, 2021.
[135]
Barsoum MW, Carey MS, Pai RN, Kalra V, Natu VR. Method of effecting cation exchange in MXene material of composite used in production of cathode of electrochemical cell, by replacing exchangeable first cation with organic cation to obtain enhanced MXene material. WO2021113509-A1, 2019.
[136]
Wu ZS, Zheng SH, Ma JX. Aqueous MXene inkjet printing conductive ink used for preparing MXene film useful in microsupercapacitors, comprises MXene nanosheet, additive and water. CN113881286-A, 2020.
[137]
Sun YM, Wang RC. Manufacturing interdigital paper-based miniature supercapacitors involves forming MXene/carbon nanotube slurry, using photoresist method to make interdigital micro-pattern grooves on filter paper to prepare interdigital electrode template. CN111863460-A, 2020.
[138]
An C, Gou JS, Kim HR, Hee LY, Da-Rae S. Manufacturing MXene film used for e.g., micro supercapacitors by preparing MXene solution, forming a MXene sheet by spraying the solution, collecting the formed MXene sheets using barrier, and attaching MXene sheets to substrate. KR2365011-B1, 2019.
[139]
Zhou S, Fang JY, Su YR, Lyu LX, Guo SY, Han PG. Preparing MXene two-dimensional material useful in preparing supercapacitors and batteries, comprises uniformly dispersing titaniumaluminum carbide and sodium hydroxide, reacting, centrifuging, obtaining lower layer precipitate, obtaining gray precipitate, and vacuum-drying gray precipitate. CN113735124-A, 2021.
[143]
He XS, Zhou L, Zhu YW, Wen XL, Li YL, Xiong BQ. MXene doped and surface-coated modified lithium ion battery cathode material comprises lithium-ion battery cathode material, MXene nanodot coating layer and MXene nanofiber material. CN112331839-A, 2020.
[144]
Wu WW, Liu HK, Wang JL. Conductive agent for lithium ion battery negative electrode slurry of lithium ion battery, has MXene titanium carbide nanosheets, and solid component whose thickness of nanosheets are in specific range respectively. CN111769281-A, 2020.
[145]
Zhang C, Ma JQ, Miao LX. Silicon-carbon composite material useful in lithium-ion battery, electronic device electric traffic, aerospace, military and medicine fields, comprises silicon/graphene composite material and MXene, where nano-particles are compounded on the MXene sheet layer. CN114335527-A, 2020.
[146]
Zhang XY, Qin JQ, Liu RP. Cobalt-layered double hydroxide/ MXene composite for cathode of lithium ion batteries, electrocatalysis, and supercapacitors, comprises MXene and cobalt layered double hydroxide grown on surface of MXene. CN113540419-B, 2021.
[147]
Deng YF, Lu ZY. Electrostatic self-assembly tin(iv) oxide@ nitrogen-doped porous carbon or MXene nano-compex material in lithium-ion battery and lithium-ion capacitor, comprises multi-level hole structure of the MXene nanosheet layer and the nitrogen doped porous carbon filled by the nano tin(iv) oxide. CN114613952-A, 2022.
[154]
Li JH, Zhang J, Rui BL, Lin L, Chang LM, Nie P. Application of MXene and its composites in sodium/potassium ion batteries. Huaxue Jinzhan 2019; 31(9): 1283.
[156]
Yuan DD, Guan SQ, Ruan ZH, Cheng C. Preparation of sodiumion battery cathode material by adding lanthanum chloride solution into MXene dispersion under stirring, centrifuging, washing and drying. CN110148725-A, 2022.
[157]
Zhang YL, Zhou JW, Xu XD, Sun HY, Liu Z. Preparing nanorhenium disulfide/MXene composite material for potassium ion battery, by dissolving rhenium source material, mixing sulfur source material, MXene nanosheets and water, heating, hydrothermally reacting, calcining and cooling. CN112018351-A, 2020.
[158]
He Q, Hu HH, Zhang DW. Preparing MXene conductive paper and paper battery useful in wear-resistant devices, microsupercapacitors, metal-ion batteries and lithium-sulfur batteries, comprises e.g. etching MAX phase material, dispersing nanolayered MXene powder in deionized water, and ultrasonically dispersing. CN114843433-A, 2021.
[162]
Niu LY, Zhang YS, Liu MC, Zhang XM. Preparation for ferrous ion supporting MXene for sodium ion battery cathode material, involves dissolving iron chloride in deionized water to obtain aqueous solution of iron chloride and dispersing MXene powder in deionized water. CN110165172-A, 2019.
,
Bei Yu and
Lingling Peng
Download PDF Flyer