Abstract
Background: Nanotechnology is a novel and developing arena of science. The building block
of nanotechnology is nanoparticles (NPs); their size is less than 100 nm. The NPs are synthesized using
two dissimilar approaches, namely top-down and bottom-up approaches. The leading methods for producing
NPs are chemical and physical methods and are frequently expensive and hypothetically dangerous to
both the surroundings and the user.
Objective: Consequently, the researchers intended to synthesize NPs using biological ingredients such as
plant extracts, bacteria, fungi, algae and yeasts. Nevertheless, the available phytochemicals in plant extracts,
compared with other microorganisms, own an extremely extraordinary capacity for metal ions reduction
within a short period, which requires a lengthier cultivation time.
Methods: In this study zinc oxide (ZnO) NPs have been produced utilizing Dill (anethum graveolens) leaf
extract. This process is an easy, one-pot, inexpensive and green process, i.e. isolated from utilizing toxic
materials.
Results: Various characterization techniques have been utilized to inspect the structure, size, morphology,
chemical composition and optical properties of the ZnO NPs. Additionally, the mechanism of formation
of ZnO NPs from Dill (anethum graveolens) leaf extract has been explained intensively.
Conclusion: This investigation revealed that Dill (anethum graveolens) leaf extract is a suitable environment
for producing nanosize ~27 nm, spherical, monodisperse, wide band gap ~ 3.56 eV, highly crystalline
and 1:1 Zn to O ratio ZnO NPs.
Graphical Abstract
[1]
Dobrovolskaia, M.A.; Germolec, D.R.; Weaver, J.L. Evaluation of nanoparticle immunotoxicity. Nat. Nanotechnol., 2009, 4(7), 411-414.
[4]
Taniguchi, N. On the basic concept of nanotechnology. Proceeding of the ICPE, 1974.
[19]
Drummer, S.; Madzimbamuto, T.F.; Chowdhury, M. Green synthesis of transition metals nanoparticle and their oxides. Materials, 2021, 14(11), 2700.
[34]
Shekhawat, M.; Ravindran, C.; Manokari, M. Biogenic production of zinc oxide nanoparticles from aqueous extracts of Duranta erecta L. World Sci. News, 2016, 28, 30.
[35]
Elumalai, K. RETRACTED: Green synthesis of zinc oxide nanoparticles using Moringa oleifera leaf extract and evaluation of its antimicrobial activity; Elsevier: Amsterdam, 2015.
[44]
Barzinjy, A.A. Characterization of ZnO nanoparticles prepared from green synthesis using Euphorbia petiolata leaves. Eurasian J. Sci. Engin., 2019, 4(3), 74-83.
[47]
Shnawa, B.H. Scolicidal activity of biosynthesized zinc oxide nanoparticles by Mentha longifolia L. leaves against Echinococcus granulosus protoscolices; Emergent materials, 2021, 1-11.
[48]
Mustafa, S.M. Biosynthesis of quantum dots and their usage in solar cells: insight from the novel researches. Int. Nano Lett., 2021, 2021, 1-13.
[50]
Barzinjy, A.A. The importance of essential-oils in the green synthesis of silver nanoparticles. J. Korean Chem. Soc., 2022, 66(4), 284-297.
[54]
Remini, H. Phytochemical analysis and antioxidant activity of Eucalyptus globulus: a comparative study between fruits and leaves extracts. J. Chem. Engin. Bioanalytical Chem., 2016, 1, 23-29.
[60]
Ochieng, P. Green route synthesis and characterization of ZnO nanoparticles using Spathodea campanulata. Int. J. Biochem. Phys, 2015, 23, 53-61.
[73]
Saravanakkumar, D. Green synthesis of ZnO nanoparticles using Trachyspermum ammi seed extract for antibacterial investigation. Pharma Chem., 2016, 8(7), 173-180.
[78]
Vidya, C. Green synthesis of ZnO nanoparticles by Calotropis gigantea. Int J Curr Eng Technol, 2013, 1(1), 118-120.