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Current Catalysis

Author(s): Dhirendra Kumar Sharma* and Seema Agarwal

DOI: 10.2174/2211544711666220517102216

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Studying Different Thermodynamic Properties of Binary Liquid Mixture of Ethyl Acetate with 1-Alkanols at 303.15K

Page: [115 - 126] Pages: 12

  • * (Excluding Mailing and Handling)

Abstract

Experimental values of ultrasonic velocity (u), density (ρ) and viscosity (η) for the binary mixtures of ethyl acetate with 1-alkanols have been measured at 303.15 K over the entire mole fraction range. Using these data, the excess isentropic compressibility (βEs), excess intermolecular free length (LEf), excess molar volume (VEm), excess free volume (VEf) and excess available volume (VEa) have been calculated. These parameters were used to study the nature and extent of intermolecular interaction between component molecules present in the binary mixtures. Excess values of isentropic compressibility, intermolecular free length, molar volume, free volume and available volume were plotted against the mole fraction of ethyl acetate over the whole composition range. From the properties of these excess parameters, the nature and strength of the interactions in these binary systems are discussed.

Keywords: Acoustical parameters, ultrasonic velocity, density, binary mixtures, ethyl acetate, 1-alkanols.

Graphical Abstract

[1]
Nikam, P.S.; Jagdale, B.S.; Sawant, A.B.; Hasan, M. Ultrasonic velocities of binary liquid mixtures. J. Pure Appl Phys., 2001, 39, 433.
[2]
Baluja, S.; Oza, S. Studies of some acoustical properties in binary solutions. Fluid Phase Equilib., 2001, 178(1-2), 233-238.
[http://dx.doi.org/10.1016/S0378-3812(00)00465-9]
[3]
Ali, A.; Nain, A.K.; Kamil, M. Thermochim. Acta, Physicochemical studies of non-aqueous binary liquid mixtures at various temperatures 1996, 274(25), 209-221.
[4]
Govindan, K.; Ravichandran, G. Excess volumes and viscosities of mixtures of nitrobenzene and certain aromatic bases. J. Solution Chem., 1996, 25(1), 75-82.
[http://dx.doi.org/10.1007/BF00972760]
[5]
Ali, A.; Nain, A.K. Study of intermolecular interaction in binary of formamide with 2-propanol, 1,2-propanediol, 1,2,3-propanetriol through ultrasonic speed measurements. Indian J. Pure Appl. Phy., 2001, 39, 421.
[6]
Baluja, S.; Oza, S. Ultrasonic studies of some derivatives of sulphonamide in dimethylformamide. Fluid Phase Equilib., 2002, 200(11), 11-18.
[http://dx.doi.org/10.1016/S0378-3812(01)00819-6]
[7]
Kaki, S.; Chandran, D.R. Studying various Thermodynamic properties of binary mixture of ethyl acetate with ethanol at 303.15 K and 313.15 K. J. Eng. Appl. Sci. (Asian Res. Publ. Netw.), 2018, 13(9), 2693-2704.
[8]
Rodriguez, A.; Canosa, J.; Tojo, J. Physical Properties and Liquid-Liquid Equilibrium and Physical Properties of the Ternary Mixture (Dimethyl Carbonate + Methanol + Cyclohexane) at 298.15 K. J. Chem. Eng. Data, 2001, 46, 846-850.
[http://dx.doi.org/10.1021/je000180s]
[9]
Nikam, P.S.; Mahale, T.R.; Hasan, M. Density and Viscosity of Binary Mixtures of Ethyl Acetate with Methanol, Ethanol, Propan- 1-ol, Propan-2-ol, Butan-1-ol, 2-Methylpropan-1-ol, and 2- Methylpropan-2-ol at (298.15, 303.15, and 308.15) K. J. Chem. Eng. Data, 1996, 41(7), 1055-1058.
[http://dx.doi.org/10.1021/je960090g]
[10]
Roy, M.N.; Sinka, A.; Biswajit, S. Excess molar volumes, viscosity deviations and isentropic compressibility of binary mixtures containing 1,3-dioxolane and mono alcohols at 303.15 K. J. Solution Chem., 2005, 34(11), 1311-1325.
[http://dx.doi.org/10.1007/s10953-005-8022-0]
[11]
Kadam, B.U.; Hiray, P.A.; Sawant, B.A.; Hasan, M. Densities, viscosities, and ultrasonic velocity studies of binary mixtures of chloroform with propan-1-oland butan-1-ol at (303.15 and 313.15) K. J. Chem. Eng. Data, 2006, 51(1), 60-63.
[http://dx.doi.org/10.1021/je050169y]
[12]
Nikam, P.S.; Mahale, T.R.; Hasan, M. Densities and Viscosities for Ethyl Acetate + Pentan-1-ol, + Hexan-1-ol, + 3,5,5- Trimethylhexan-1-ol, + Heptan-1-ol, + Octan-1-ol, and + Decan-1- ol at (298.15, 303.15, and 308.15) K. J. Chem. Eng. Data, 1998, 43(3), 436-440.
[http://dx.doi.org/10.1021/je970253g]
[13]
Al-Kandary, A.J.; Al-Jimaz, A.S.; Abdul-Latif, A.M. Densities, Viscosities, Speeds of Sound and Refractive Indices of Binary Mixtures of Tetrahydrofuran with 1-Hexanol, 1-Heptanol, 1-Octanol, 1-Nonanol and 1-Decanol at 298.15, 303.15, 308.15 and 313.15 K. Phys. Chem. Liquids, 2009, 47(2), 210-224.
[http://dx.doi.org/10.1080/00319100802123152]
[14]
Dubey, G.P.; Sharma, M. Excess Volumes, Densities, Speeds of Sound, and Viscosities for the Binary Systems of 1-Octanol with Hexadecane and Squalane at (298.15, 303.15 and 308.15) K. Int. J. Thermophys., 2008, 29(4), 1361-1375.
[http://dx.doi.org/10.1007/s10765-008-0491-0]
[15]
Elangovan, S.; Mullainathan, S. Ultrasonic Studies of Intermolecular Interaction in Binary Mixture of n-Methyl Formate with 1-Propanol at Various Temperatures. Indian J. Phys. Proc. Indian Assoc. Cultiv. Sci., 2013, 87(7), 659-664.
[http://dx.doi.org/10.1007/s12648-013-0288-2]
[16]
Yasmin, M.; Singh, K.P.; Parveen, S.; Gupta, M.; Shukla, J.P. Thermoacoustical excess properties of binaryliquid mixtures-a comparative experimental and theoretical study. Acta Phys. Pol. A, 2009, 115(5), 890-900.
[http://dx.doi.org/10.12693/APhysPolA.115.890]
[17]
Ali, A.; Hyder, S.; Tariq, M. Measurements of the properties of binary mixtures of dimethylsulphoxide (DMSO) with 1-alkanols (C4, C6, C7) at 303.15. Int. J. Thermophys., 2005, 26(5), 1537-1548.
[http://dx.doi.org/10.1007/s10765-005-8102-9]
[18]
Yadava, R.R.; Singh, V.N.; Yadava, S.S. Excess Volume of Mixing for Binary Mixtures of Some Nitroalkanes and Symmetrical Aromatic Hydrocarbons J. J. Chem. Eng. Data, 1994, 39(4), 705-707.
[http://dx.doi.org/10.1021/je00016a014]
[19]
Sathyanarayan, B.; Ranjith Kumar, B. SavithaJyostna, T.; Satyanarayan, N. Densities and viscosities of binary liquid mixtures of N-methylacetamide with some chloroethanes and chloroethenes at T = 308.15 K. J. Chem. Thermodyn., 2007, 39(1), 16-21.
[http://dx.doi.org/10.1016/j.jct.2006.06.009]
[20]
Suindells, J.R.; Godfray, T.B. Studies on thermodynamics and transport properties of two binary mixtures formed by water, methanol and tetra hydro furan at different temperature. J. Res. Natl. Bur. Stand., 1952, 48, 1.
[21]
Nikam, P.S.; Shirsat, L.N.; Hasan, M. Density and viscosity studies of binary mixtures of acetonitrile with methanol, ethanol, propan-1- ol, propan-2-ol, butan-1-ol, 2-methylpropan-1-ol, and 2- methylpropan-2-ol at (298.15, 303.15, 308.15, and 313.15) K. J. Chem. Eng. Data, 1998, 43(5), 732-737.
[http://dx.doi.org/10.1021/je980028e]
[22]
Bingham, E.C. Fluidity and Plasticity; McGraw Hill: New York, 1922.
[23]
Macleod, D.B. On a direct calculation of the viscosity of a liquid, both under ordinary pressures and high pressures, from the viscosity of its vapour, on the basis of a new equation of state. Trans. Faraday Soc., 1945, 41, 771-777.
[http://dx.doi.org/10.1039/tf9454100771]
[24]
Suryanarayana, C.V.; Kuppusami, J. Free volume and internal pressure of liquid from ultrasonic velocity. J. Acoust. Soc. Ind., 1976, 4, 75-81.
[25]
Jacobson, B. Ultrasonic velocity in liquids and liquid mixtures. J. Chem. Phys., 1952, 20(5), 927-928.
[http://dx.doi.org/10.1063/1.1700615]
[26]
Jacobson, B. Intermolecular Free Lengths in Liquids in Relation to Compressibility, Surface Tension and Viscosity. Acta Chem. Scand., 1952, 5, 1214-1216.
[http://dx.doi.org/10.3891/acta.chem.scand.05-1214]
[27]
Vekatesu, P.; Chandra Sekhar, G.; Prabhakar Rao, M.V. Ultrasonic studies of N,N-dimethylformamide + cyclohexanone + 1-alkanols at 303.15 K. Phys. Chem. Liquids, 2006, 44(3), 287-291.
[http://dx.doi.org/10.1080/00319100600576718]
[28]
Fort, R.J.; Moore, W.R. Adiabatic compressibilities in binary liquid mixtures. Trans. Faraday Soc., 1965, 61, 2102-2110.
[http://dx.doi.org/10.1039/tf9656102102]
[29]
Garcio, B.; Aparicio, S.; Navarro, A.M.; Alcalde, R.; Leal, J.M. Measurements and modeling of thermophysical behavior of (C1-C4) Alkylbenzoate(C1-C11) Alkan-1-ol mixed solvents. J. Phys. Chem. B, 2004, 108(40), 15841-15850.
[http://dx.doi.org/10.1021/jp0485439]
[30]
Mehra, R.; Gaur, A.K. Study of a Binary Liquid Mixture of Diethylamine and 1-Decanol and Validation of Theoretical Approaches of Sound Speed at Different Temperatures. J. Chem. Eng. Data, 2008, 53(3), 863-866.
[http://dx.doi.org/10.1021/je700619q]
[31]
Prasad, N.; Ray, R.P.K.; Kumar, M. Ultrasonic study of binary solutions of tri ethyl amine with alcohols. J. Pure Appl. Ultrason., 2014, 36, 97-103.