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Current Organic Synthesis

Author(s): Biljana Šmit*, Petar B. Stanić and Nenad Janković*

DOI: 10.2174/1570179418666210917152537

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Selenocyclization by Formation of Carbon-nitrogen Bonds

Page: [293 - 316] Pages: 24

  • * (Excluding Mailing and Handling)

Abstract

Selenium promoted-cyclization of unsaturated substrates containing internal nitrogen nucleophiles, such as different amines and amides, including the examples of its application in the synthesis of more complex polycyclic compounds is reviewed. Selenocyclization reactions of some more specific polyfunctional substrates, like Biginelli hybrids and hydantoins, are also covered.

Keywords: Selenium reagents, cyclization, cyclic amines, cyclic amides, lactamisation, fused rings.

Graphical Abstract

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