Mini-Reviews in Organic Chemistry

Author(s): Kaijun Chen, Dayun Huang* and Xiangyu Sun*

DOI: 10.2174/1570193X18666210810154051

Strategy Analysis of Ynones’ Radical Reactions

Page: [432 - 438] Pages: 7

  • * (Excluding Mailing and Handling)

Abstract

This review highlights the multifaceted synthetic applications of ynones in radical reactions. Substantial progress has been made over the last decade (2010-2020) in the utilization of ynones. Herein, the chemistry of ynones is divided into three sections based on the classes of critical mechanistic insights: (1) radical addition and intramolecular cyclization; (2) radical addition and intermolecular annulation; (3) radical addition and coupling. We hope that this review will promote future research in this area.

Keywords: Radical, ynone, radical cyclization, reaction coupling, tandem reaction, intramolecular cyclization.

Graphical Abstract

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