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Letters in Organic Chemistry

Author(s): Prashant Gautam and Vivek Srivastava*

DOI: 10.2174/1570178617999200723124636

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Heck Cross-Coupling Reactions in Ionic Liquid mediated Pd Nanocatalysts

Page: [359 - 372] Pages: 14

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Abstract

We straightforwardly synthesized 18 different types of palladium nanoparticles by using a series of palladium metal precursors and ionic liquids. All the materials went for XRD, TEM, and ICPOES analysis, before going to Heck cross-coupling reaction as a catalyst. We evaluated the catalytic performance of our developed IL#Pd MNP catalyst over Heck cross-coupling reaction between different terminal olefins with various 3-iodo-benzopyrones, including sterically hindered, electron-rich, electron neutral and electron-deficient systems. We obtained the Heck cross-coupling reaction product in good to average yield under phosphine free reaction condition with an added advantage of 6 times catalyst recycling.

Keywords: Ionic Liquid, palladium nanoparticles, Heck cross-coupling reaction, cross-coupling reaction, 3-iodo-benzopyrones.

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