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Current Pharmaceutical Design

Author(s): Nasrullah Shah*, Saba Gul and Mazhar Ul-Islam*

DOI: 10.2174/1381612825666191009153259

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Core-Shell Molecularly Imprinted Polymer Nanocomposites for Biomedical and Environmental Applications

Page: [3633 - 3644] Pages: 12

  • * (Excluding Mailing and Handling)

Abstract

Core-shell polymers represent a class of composite particles comprising of minimum two dissimilar constituents, one at the center known as a core which is occupied by the other called shell. Core-shell molecularly imprinting polymers (CSMIPs) are composites prepared via printing a template molecule (analyte) in the coreshell assembly followed by their elimination to provide the everlasting cavities specific to the template molecules. Various other types of CSMIPs with a partial shell, hollow-core and empty-shell are also prepared. Numerous methods have been reported for synthesizing the CSMIPs. CSMIPs composites could develop the ability to identify template molecules, increase the relative adsorption selectivity and offer higher adsorption capacity. Keen features are measured that permits these polymers to be utilized in numerous applications. It has been developed as a modern technique with the probability for an extensive range of uses in selective adsorption, biomedical fields, food processing, environmental applications, in utilizing the plant's extracts for further applications, and sensors. This review covers the approaches of developing the CSMIPs synthetic schemes, and their application with special emphasis on uses in the biomedical field, food care subjects, plant extracts analysis and in environmental studies.

Keywords: Core-shell MIPs, synthesis, applications, biomedical, environmental, CSMIPs composites.

[1]
Wang X-N, Liang R-P, Meng X-Y, Qiu J-D. One-step synthesis of mussel-inspired molecularly imprinted magnetic polymer as stationary phase for chip-based open tubular capillary electrochromatography enantioseparation. J Chromatogr A 2014; 1362: 301-8..
[http://dx.doi.org/10.1016/j.chroma.2014.08.044] [PMID: 25182855]
[2]
Tang Y, Liu H, Gao J, et al. Upconversion particle@Fe3O4@molecularly imprinted polymer with controllable shell thickness as high-performance fluorescent probe for sensing quinolones. Talanta 2018; 181: 95-103.
[http://dx.doi.org/10.1016/j.talanta.2018.01.006] [PMID: 29426547]
[3]
Ansari S. Application of magnetic molecularly imprinted polymer as a versatile and highly selective tool in food and environmental analysis: recent developments and trends. Trends Analyt Chem 2017; 90: 89-106.
[http://dx.doi.org/10.1016/j.trac.2017.03.001]
[4]
Shah N, Rehan T, Park JK. Adsorptive molecularly imprinted composite membranes for chiral separation of phenylalanine. Pol J Chem Technol 2016; 18: 22-9.
[http://dx.doi.org/10.1515/pjct-2016-0044]
[5]
Shah N, Ul-Islam M, Haneef M, Park JK. A brief overview of molecularly imprinted polymers: from basics to applications. J Pharm Res 2012; 5: 3309-17.
[6]
Shah N, Ulislam M, Ha J, Park JK. Chiral separation of phenylalanine using D-phenylalanine imprinted membrane containing L-phenylalanine imprinted submicron/nanoscale beads. J Pharm Res 2012; 5: 4425-33.
[7]
Shah N, Ha JH, Ul-Islam M, Park JK. Highly improved adsorption selectivity of L-phenylalanine imprinted polymeric submicron/nanoscale beads prepared by modified suspension polymerization. Korean J Chem Eng 2011; 28: 1936.
[http://dx.doi.org/10.1007/s11814-011-0043-3]
[8]
Wan L, Chen Z, Huang C, Shen X. Core-shell molecularly imprinted particles. Trends Analyt Chem 2017; 95: 110-21.
[http://dx.doi.org/10.1016/j.trac.2017.08.010]
[9]
Niu M, Pham-Huy C, He H. Core-shell nanoparticles coated with molecularly imprinted polymers: a review. Mikrochim Acta 2016; 183: 2677-95.
[http://dx.doi.org/10.1007/s00604-016-1930-4]
[10]
Javidi J, Esmaeilpour M, Khansari MR. Synthesis, characterization and application of core-shell magnetic molecularly imprinted polymers for selective recognition of clozapine from human serum. RSC Advances 2015; 5: 73268-78.
[http://dx.doi.org/10.1039/C5RA10356H]
[11]
Li L, He X, Chen L, Zhang Y. Preparation of core-shell magnetic molecularly imprinted polymer nanoparticles for recognition of bovine hemoglobin. Chem Asian J 2009; 4(2): 286-93.
[http://dx.doi.org/10.1002/asia.200800300] [PMID: 19040251]
[12]
Carter S, Lu S-Y, Rimmer S. Core-shell molecularly imprinted polymer colloids. Supramol Chem 2003; 15: 213-20.
[http://dx.doi.org/10.1080/1061027031000078284]
[13]
Gonzato C, Courty M, Pasetto P, Haupt K. Magnetic molecularly imprinted polymer nanocomposites via surface-initiated RAFT polymerization. Adv Funct Mater 2011; 21: 3947-53.
[http://dx.doi.org/10.1002/adfm.201100466]
[14]
Deiminiat B, Razavipanah I, Rounaghi GH, Arbab-Zavar MH. A novel electrochemical imprinted sensor for acetylsalicylic acid based on polypyrrole, sol-gel and SiO2@ Au core-shell nanoparticles. Sens Actuators B Chem 2017; 244: 785-95.
[http://dx.doi.org/10.1016/j.snb.2017.01.059]
[15]
He J, Shang H, Zhang X, Sun X. Synthesis and application of ion imprinting polymer coated magnetic multi-walled carbon nanotubes for selective adsorption of nickel ion. Appl Surf Sci 2018; 428: 110-7.
[http://dx.doi.org/10.1016/j.apsusc.2017.09.123]
[16]
Li J, Zhou Q, Yuan Y, Wu Y. Iron-based magnetic molecularly imprinted polymers and their application in removal and determination of di-n-pentyl phthalate in aqueous media. R Soc Open Sci 2017; 4(8)170672
[http://dx.doi.org/10.1098/rsos.170672] [PMID: 28879009]
[17]
Ding M, Wu X, Yuan L, et al. Synthesis of core-shell magnetic molecularly imprinted polymers and detection of sildenafil and vardenafil in herbal dietary supplements. J Hazard Mater 2011; 191(1-3): 177-83.
[http://dx.doi.org/10.1016/j.jhazmat.2011.04.058] [PMID: 21555181]
[18]
Lu C-H, Zhou W-H, Han B, Yang H-H, Chen X, Wang X-R. Surface-imprinted core-shell nanoparticles for sorbent assays. Anal Chem 2007; 79(14): 5457-61.
[http://dx.doi.org/10.1021/ac070282m] [PMID: 17563116]
[19]
Yan H, Cheng X, Sun N. Synthesis of multi-core-shell magnetic molecularly imprinted microspheres for rapid recognition of dicofol in tea. J Agric Food Chem 2013; 61(11): 2896-901.
[http://dx.doi.org/10.1021/jf400847b] [PMID: 23432386]
[20]
Phutthawong N, Pattarawarapan M. Facile synthesis of magnetic molecularly imprinted polymers for caffeine via ultrasound-assisted precipitation polymerization. Polym Bull 2013; 70: 691-705.
[http://dx.doi.org/10.1007/s00289-012-0836-5]
[21]
Wang Z, Qian Y, Wei X, Zhang Y, Wu G, Lu X. An “on-off” electrochemiluminescence biosensor based on molecularly imprinted polymer and recycling amplifications for determination of dopamine. Electrochim Acta 2017; 250: 309-19.
[http://dx.doi.org/10.1016/j.electacta.2017.08.076]
[22]
Ma Y, Xu S, Wang S, Wang L. Luminescent molecularly-imprinted polymer nanocomposites for sensitive detection. Trends Analyt Chem 2015; 67: 209-16.
[http://dx.doi.org/10.1016/j.trac.2015.01.012]
[23]
Li Y, Li X, Chu J, Dong C, Qi J, Yuan Y. Synthesis of core-shell magnetic molecularly imprinted polymer by the surface RAFT polymerization for the fast and selective removal of endocrine disrupting chemicals from aqueous solutions. Environ Pollut 2010; 158(6): 2317-23.
[http://dx.doi.org/10.1016/j.envpol.2010.02.007] [PMID: 20199830]
[24]
Guo Y, Yang Y, Zhang L, Guo TY. Core/shell molecular imprinting microparticles prepared using RAFT technology for degradation of paraoxon. Macromol Res 2011; 19: 1202.
[http://dx.doi.org/10.1007/s13233-011-1107-2]
[25]
Chang L, Li Y, Chu J, Qi J, Li X. Preparation of core-shell Molecularly imprinted polymer via the combination of reversible addition-fragmentation chain transfer polymerization and click reaction. Anal Chim Acta 2010; 680(1-2): 65-71.
[http://dx.doi.org/10.1016/j.aca.2010.09.017] [PMID: 20969993]
[26]
Chen F, Wang J, Chen H, Lu R, Xie X. Microwave-assisted RAFT polymerization of well-constructed magnetic surface molecularly imprinted polymers for specific recognition of benzimidazole residues. Appl Surf Sci 2018; 435: 247-55.
[http://dx.doi.org/10.1016/j.apsusc.2017.11.061]
[27]
Shao Y, Zhou L, Wu Q, Bao C, Liu M. Preparation of novel magnetic molecularly imprinted polymers nanospheres via reversible addition - fragmentation chain transfer polymerization for selective and efficient determination of tetrabromobisphenol A. J Hazard Mater 2017; 339: 418-26.
[http://dx.doi.org/10.1016/j.jhazmat.2017.06.017] [PMID: 28686932]
[28]
Yu P, Sun Q, Tan Z, et al. Magnetic molecularly imprinted polymer beads obtained by suspension polymerization for the adsorption of 2, 4, 6-trichlorophenol from an aqueous solution in a fixed-bed column. Adsorpt Sci Technol 2015; 33: 321-36.
[http://dx.doi.org/10.1260/0263-6174.33.3.321]
[29]
Barahona F, Turiel E, Cormack PA, Martín-Esteban A. Synthesis of core-shell molecularly imprinted polymer microspheres by precipitation polymerization for the inline molecularly imprinted solid-phase extraction of thiabendazole from citrus fruits and orange juice samples. J Sep Sci 2011; 34(2): 217-24.
[http://dx.doi.org/10.1002/jssc.201000277] [PMID: 21246728]
[30]
Uzuriaga-Sánchez RJ, Wong A, Khan S, Pividori MI, Picasso G, Sotomayor MDPT. Synthesis of a new magnetic-MIP for the selective detection of 1-chloro-2,4-dinitrobenzene, a highly allergenic compound. Mater Sci Eng C 2017; 74: 365-73.
[http://dx.doi.org/10.1016/j.msec.2016.12.019] [PMID: 28254306]
[31]
Lu S, Cheng G, Pang X. Preparation of molecularly imprinted Fe3O4/P (St‐DVB) composite beads with magnetic susceptibility and their characteristics of molecular recognition for amino acid. J Appl Polym Sci 2003; 89: 3790-6.
[http://dx.doi.org/10.1002/app.12530]
[32]
Zhang Y, Liu R, Hu Y, Li G. Microwave heating in preparation of magnetic molecularly imprinted polymer beads for trace triazines analysis in complicated samples. Anal Chem 2009; 81(3): 967-76.
[http://dx.doi.org/10.1021/ac8018262] [PMID: 19178336]
[33]
Zhang Y, Li Y, Hu Y, Li G, Chen Y. Preparation of magnetic indole-3-acetic acid imprinted polymer beads with 4-vinylpyridine and β-cyclodextrin as binary monomer via microwave heating initiated polymerization and their application to trace analysis of auxins in plant tissues. J Chromatogr A 2010; 1217(47): 7337-44.
[http://dx.doi.org/10.1016/j.chroma.2010.09.059] [PMID: 20950814]
[34]
Wang X, Mao H, Huang W, et al. Preparation of magnetic imprinted polymer particles via microwave heating initiated polymerization for selective enrichment of 2-amino-4-nitrophenol from aqueous solution. Chem Eng J 2011; 178: 85-92.
[http://dx.doi.org/10.1016/j.cej.2011.10.015]
[35]
Liu Y, He Y, Jin Y, Huang Y, Liu G, Zhao R. Preparation of monodispersed macroporous core-shell molecularly imprinted particles and their application in the determination of 2,4-dichlorophenoxyacetic acid. J Chromatogr A 2014; 1323: 11-7.
[http://dx.doi.org/10.1016/j.chroma.2013.11.002] [PMID: 24300087]
[36]
Gul S, Shah N, Arain MB, et al. Fabrication of magnetic core shell particles coated with phenylalanine imprinted polymer. Polym Test 2019; 75: 262-9.
[http://dx.doi.org/10.1016/j.polymertesting.2019.02.023]
[37]
Wang Y, Liu Q, Rong F, Fu D. A facile method for grafting of bisphenol A imprinted polymer shells onto poly (divinylbenzene) microspheres through precipitation polymerization. Appl Surf Sci 2011; 257: 6704-10.
[http://dx.doi.org/10.1016/j.apsusc.2011.02.105]
[38]
Men H-F, Liu H-Q, Zhang Z-L, et al. Synthesis, properties and application research of atrazine Fe3O4@SiO2 magnetic molecularly imprinted polymer. Environ Sci Pollut Res Int 2012; 19(6): 2271-80.
[http://dx.doi.org/10.1007/s11356-011-0732-9] [PMID: 22246642]
[39]
Pérez-Moral N, Mayes AG. Noncovalent imprinting in the shell of core-shell nanoparticles. Langmuir 2004; 20(9): 3775-9.
[http://dx.doi.org/10.1021/la0356755] [PMID: 15875414]
[40]
Wang X, Ding X, Zheng Z, Hu X, Cheng X, Peng Y. Magnetic molecularly imprinted polymer particles synthesized by suspension polymerization in silicone oil. Macromol Rapid Commun 2006; 27: 1180-4.
[http://dx.doi.org/10.1002/marc.200600211]
[41]
Wang X, Kang Q, Shen D, Zhang Z, Li J, Chen L. Novel monodisperse molecularly imprinted shell for estradiol based on surface imprinted hollow vinyl-SiO2 particles. Talanta 2014; 124: 7-13.
[http://dx.doi.org/10.1016/j.talanta.2014.02.040] [PMID: 24767439]
[42]
Pan J, Qu Q, Cao J, et al. Molecularly imprinted polymer foams with well-defined open-cell structure derived from Pickering HIPEs and their enhanced recognition of λ-cyhalothrin. Chem Eng J 2014; 253: 138-47.
[http://dx.doi.org/10.1016/j.cej.2014.05.031]
[43]
Yang J, Li Y, Wang J, et al. Molecularly imprinted polymer microspheres prepared by Pickering emulsion polymerization for selective solid-phase extraction of eight bisphenols from human urine samples. Anal Chim Acta 2015; 872: 35-45.
[http://dx.doi.org/10.1016/j.aca.2015.02.058] [PMID: 25892067]
[44]
Wang X, Huang P, Ma X, Wang H, Lu X, Du X. Preparation and evaluation of magnetic core-shell mesoporous molecularly imprinted polymers for selective adsorption of tetrabromobisphenol S. Talanta 2017; 166: 300-5.
[http://dx.doi.org/10.1016/j.talanta.2017.01.067] [PMID: 28213238]
[45]
Zhu S, Gan N, Pan D, et al. Extraction of tributyltin by magnetic molecularly imprinted polymers. Mikrochim Acta 2013; 180: 545-53.
[http://dx.doi.org/10.1007/s00604-013-0962-2]
[46]
Liu M, Li X-Y, Li J-J, et al. Synthesis of magnetic molecularly imprinted polymers for the selective separation and determination of metronidazole in cosmetic samples. Anal Bioanal Chem 2015; 407(13): 3875-80.
[http://dx.doi.org/10.1007/s00216-015-8592-7] [PMID: 25749799]
[47]
Liu D, Yang Q, Jin S, et al. Core-shell molecularly imprinted polymer nanoparticles with assistant recognition polymer chains for effective recognition and enrichment of natural low-abundance protein. Acta Biomater 2014; 10(2): 769-75.
[http://dx.doi.org/10.1016/j.actbio.2013.10.007] [PMID: 24140608]
[48]
Cao J, Zhang X, He X, Chen L, Zhang Y. The synthesis of magnetic lysozyme-imprinted polymers by means of distillation-precipitation polymerization for selective protein enrichment. Chem Asian J 2014; 9(2): 526-33.
[http://dx.doi.org/10.1002/asia.201300937] [PMID: 24203562]
[49]
Du C, Hu X, Guan P, et al. Synthesis of water-compatible surface-imprinted composite microspheres with core-shell structure for selective recognition of thymopentin from aqueous solution. J Mater Sci 2015; 50: 427-38.
[http://dx.doi.org/10.1007/s10853-014-8602-8]
[50]
Han S, Li X, Wang Y, Chen S. Multifunctional imprinted polymers based on CdTe/CdS and magnetic graphene oxide for selective recognition and separation of pt-octylphenol. Chem Eng J 2015; 271: 87-95.
[http://dx.doi.org/10.1016/j.cej.2015.02.080]
[51]
Tan L, He R, Chen K, et al. Ultra-high performance liquid chromatography combined with mass spectrometry for determination of aflatoxins using dummy molecularly imprinted polymers deposited on silica-coated magnetic nanoparticles. Mikrochim Acta 2016; 183: 1469-77.
[http://dx.doi.org/10.1007/s00604-016-1790-y]
[52]
Tian J, Bai J, Peng Y, et al. A core-shell-structured molecularly imprinted polymer on upconverting nanoparticles for selective and sensitive fluorescence sensing of sulfamethazine. Analyst (Lond) 2015; 140(15): 5301-7.
[http://dx.doi.org/10.1039/C5AN00579E] [PMID: 26075380]
[53]
Chen L, Zhang X, Xu Y, et al. Determination of fluoroquinolone antibiotics in environmental water samples based on magnetic molecularly imprinted polymer extraction followed by liquid chromatography-tandem mass spectrometry. Anal Chim Acta 2010; 662(1): 31-8.
[http://dx.doi.org/10.1016/j.aca.2010.01.001] [PMID: 20152262]
[54]
Wang Z, Cao X. Preparation of core-shell molecular imprinting polymer for lincomycin A and its application in chromatographic column. Process Biochem 2015; 50: 1136-45.
[http://dx.doi.org/10.1016/j.procbio.2015.04.013]
[55]
Gutierrez-Climente R, Gomez-Caballero A, Guerreiro A, et al. Molecularly imprinted nanoparticles grafted to porous silica as chiral selectors in liquid chromatography. J Chromatogr A 2017; 1508: 53-64.
[http://dx.doi.org/10.1016/j.chroma.2017.05.066] [PMID: 28599860]
[56]
Chen J, Liang R-P, Wang X-N, Qiu J-D. A norepinephrine coated magnetic molecularly imprinted polymer for simultaneous multiple chiral recognition. J Chromatogr A 2015; 1409: 268-76.
[http://dx.doi.org/10.1016/j.chroma.2015.07.052] [PMID: 26206627]
[57]
Zhang Z, Niu D, Li Y, Shi J. Magnetic, core-shell structured and surface molecularly imprinted polymers for the rapid and selective recognition of salicylic acid from aqueous solutions. Appl Surf Sci 2018; 435: 178-86.
[http://dx.doi.org/10.1016/j.apsusc.2017.11.033]
[58]
Duan GW, Zhang J, Li Y, Xu YM, Yin F, Fu YZ. The preparation of Fe3O4/molecular-imprinted nanocomposite and the application on the recognition and separation of glyphosate. Inorg Nano-Met Chem 2017; 47: 481-7.
[http://dx.doi.org/10.1080/15533174.2016.1186052]
[59]
Fan J-P, Xu X-K, Xu R, Zhang X-H, Zhu J-H. Preparation and characterization of molecularly imprinted polymer functionalized with core/shell magnetic particles (Fe3O4@ SiO2@ MIP) for the simultaneous recognition and enrichment of four taxoids in Taxus× media. Chem Eng J 2015; 279: 567-77.
[http://dx.doi.org/10.1016/j.cej.2015.05.045]
[60]
Miao SS, Wu MS, Zuo HG, et al. Core-shell magnetic molecularly imprinted polymers as sorbent for sulfonylurea herbicide residues. J Agric Food Chem 2015; 63(14): 3634-45.
[http://dx.doi.org/10.1021/jf506239b] [PMID: 25797565]
[61]
Xie X, Wei F, Chen L, Wang S. Preparation of molecularly imprinted polymers based on magnetic nanoparticles for the selective extraction of protocatechuic acid from plant extracts. J Sep Sci 2015; 38(6): 1046-52.
[http://dx.doi.org/10.1002/jssc.201401142] [PMID: 25641806]
[62]
Jia X, Li H, Luo J, et al. Rational design of core-shell molecularly imprinted polymer based on computational simulation and Doehlert experimental optimization: application to the separation of tanshinone IIA from Salvia miltiorrhiza Bunge. Anal Bioanal Chem 2012; 403(9): 2691-703.
[http://dx.doi.org/10.1007/s00216-012-6078-4] [PMID: 22576658]
[63]
Machyňáková A, Hroboňová K. Preparation and application of magnetic molecularly imprinted polymers for the selective extraction of coumarins from food and plant samples. Anal Methods 2017; 9: 2168-76.
[http://dx.doi.org/10.1039/C7AY00502D]
[64]
Qi Y, Li G, Wei C, Zhao L, Gong B. Preparation of magnetic Molecularly imprinted polymer for melamine and its application in milk sample analysis by HPLC. J Biomed Sci 2016; 5: 2.
[65]
Zhang Z, Zhang M, Luo L, et al. Synthesis and application of core-shell complex-imprinted polymer for the solid-phase extraction of melamine from dairy products. J Sep Sci 2010; 33(17-18): 2854-61.
[http://dx.doi.org/10.1002/jssc.201000264] [PMID: 20665767]
[66]
Chen L, Li B. Magnetic Molecularly imprinted polymer extraction of chloramphenicol from honey. Food Chem 2013; 141(1): 23-8.
[http://dx.doi.org/10.1016/j.foodchem.2013.02.085] [PMID: 23768321]
[67]
Su X, Li X, Li J, et al. Synthesis and characterization of core-shell magnetic molecularly imprinted polymers for solid-phase extraction and determination of Rhodamine B in food. Food Chem 2015; 171: 292-7.
[http://dx.doi.org/10.1016/j.foodchem.2014.09.024] [PMID: 25308672]
[68]
Lu F, Li H, Sun M, et al. Flow injection chemiluminescence sensor based on core-shell magnetic molecularly imprinted nanoparticles for determination of sulfadiazine. Anal Chim Acta 2012; 718: 84-91.
[http://dx.doi.org/10.1016/j.aca.2011.12.054] [PMID: 22305902]
[69]
Pan S-D, Ye M-J, Gao G-S, et al. Synthesis of a monodisperse well-defined core-shell magnetic molecularly-imprinted polymer prior to LC-MS/MS for fast and sensitive determination of mycotoxin residues in rice. Anal Methods 2017; 9: 5281-92.
[http://dx.doi.org/10.1039/C7AY01444A]
[70]
Kiani A, Ghorbani M. Synthesis of core-shell magnetic ion-imprinted polymer nanospheres for selective solid-phase extraction of Pb2+ from biological, food, and wastewater samples. J Dispers Sci Technol 2017; 38: 1041-8.
[http://dx.doi.org/10.1080/01932691.2016.1219666]
[71]
Kong X, Gao R, He X, Chen L, Zhang Y. Synthesis and characterization of the core-shell magnetic molecularly imprinted polymers (Fe3O4@MIPs) adsorbents for effective extraction and determination of sulfonamides in the poultry feed. J Chromatogr A 2012; 1245: 8-16.
[http://dx.doi.org/10.1016/j.chroma.2012.04.061] [PMID: 22663976]
[72]
Yang W, Niu D, Ni X, Zhou Z, Xu W, Huang W. Core-shell magnetic molecularly imprinted polymer prepared for selectively removed indole from fuel oil. Adv Polym Technol 2017; 36: 168-76.
[http://dx.doi.org/10.1002/adv.21596]
[73]
Wei X, Zhou Z, Hao T, et al. Highly-controllable imprinted polymer nanoshell at the surface of silica nanoparticles based room-temperature phosphorescence probe for detection of 2,4-dichlorophenol. Anal Chim Acta 2015; 870: 83-91.
[http://dx.doi.org/10.1016/j.aca.2015.02.025] [PMID: 25819790]
[74]
Harsini NN, Ansari M, Kazemipour M. Synthesis of molecularly imprinted polymer on magnetic core-shell silica nanoparticles for recognition of Congo red. Eurasian J Anal Chem 2018; 13(3)em20
[75]
Liu B, Han M, Guan G, Wang S, Liu R, Zhang Z. Highly-controllable molecular imprinting at superparamagnetic iron oxide nanoparticles for ultrafast enrichment and separation. J Phys Chem C 2011; 115: 17320-7.
[http://dx.doi.org/10.1021/jp205327q]
[76]
Ahmad I, Kamal T, Khan SB, Asiri AM. An efficient and easily retrievable dip catalyst based on silver nanoparticles/chitosan-coated cellulose filter paper. Cellulose 2016; 23: 3577-88.
[http://dx.doi.org/10.1007/s10570-016-1053-4]
[77]
Ahmed MS, Kamal T, Khan SA, et al. Assessment of anti-bacterial Ni-Al/chitosan composite spheres for adsorption assisted photo-degradation of organic pollutants. Curr Nanosci 2016; 12: 569-75.
[http://dx.doi.org/10.2174/1573413712666160204000517]
[78]
Ali F, Khan SB, Kamal T, Alamry KA, Asiri AM. Chitosan-titanium oxide fibers supported zero-valent nanoparticles: highly efficient and easily retrievable catalyst for the removal of organic pollutants. Sci Rep 2018; 8(1): 6260.
[http://dx.doi.org/10.1038/s41598-018-24311-4] [PMID: 29674721]
[79]
Ali F, Khan SB, Kamal T, Alamry KA, Asiri AM, Sobahi TRA. Chitosan coated cotton cloth supported zero-valent nanoparticles: Simple but economically viable, efficient and easily retrievable catalysts. Sci Rep 2017; 7(1): 16957.
[http://dx.doi.org/10.1038/s41598-017-16815-2] [PMID: 29209040]
[80]
Ali F, Khan SB, Kamal T, et al. Synthesis and characterization of metal nanoparticles templated chitosan-SiO2 catalyst for the reduction of nitrophenols and dyes. Carbohydr Polym 2018; 192: 217-30.
[http://dx.doi.org/10.1016/j.carbpol.2018.03.029] [PMID: 29691016]
[81]
Ali F, Khan SB, Kamal T, Anwar Y, Alamry KA, Asiri AM. Anti-bacterial chitosan/zinc phthalocyanine fibers supported metallic and bimetallic nanoparticles for the removal of organic pollutants. Carbohydr Polym 2017; 173: 676-89.
[http://dx.doi.org/10.1016/j.carbpol.2017.05.074] [PMID: 28732913]
[82]
Ali F, Khan SB, Kamal T, Anwar Y, Alamry KA, Asiri AM. Bactericidal and catalytic performance of green nanocomposite based-on chitosan/carbon black fiber supported monometallic and bimetallic nanoparticles. Chemosphere 2017; 188: 588-98.
[http://dx.doi.org/10.1016/j.chemosphere.2017.08.118] [PMID: 28917211]
[83]
Ali N. Awais, Kamal T, et al. Chitosan-coated cotton cloth supported copper nanoparticles for toxic dye reduction. Int J Biol Macromol 2018; 111: 832-8.
[http://dx.doi.org/10.1016/j.ijbiomac.2018.01.092] [PMID: 29355628]
[84]
Haider A, Haider S, Kang IK, et al. A novel use of cellulose based filter paper containing silver nanoparticles for its potential application as wound dressing agent. Int J Biol Macromol 2018; 108: 455-61.
[http://dx.doi.org/10.1016/j.ijbiomac.2017.12.022] [PMID: 29222019]
[85]
Haider S, Kamal T, Khan SB, et al. Natural polymers supported copper nanoparticles for pollutants degradation. Appl Surf Sci 2016; 387: 1154-61.
[http://dx.doi.org/10.1016/j.apsusc.2016.06.133]
[86]
Kamal T. Aminophenols formation from nitrophenols using agar biopolymer hydrogel supported CuO nanoparticles catalyst. Polym Test 2019; 77105896
[http://dx.doi.org/10.1016/j.polymertesting.2019.105896]
[87]
Kamal T, Ahmad I, Khan SB, Asiri AM. Synthesis and catalytic properties of silver nanoparticles supported on porous cellulose acetate sheets and wet-spun fibers. Carbohydr Polym 2017; 157: 294-302.
[http://dx.doi.org/10.1016/j.carbpol.2016.09.078] [PMID: 27987930]
[88]
Kamal T, Ahmad I, Khan SB, Asiri AM. Agar hydrogel supported metal nanoparticles catalyst for pollutants degradation in water. Desalination Water Treat 2018; 136: 290-8.
[http://dx.doi.org/10.5004/dwt.2018.23230]
[89]
Kamal T, Ali N, Naseem AA, Khan SB, Asiri AM. Polymer nanocomposite membranes for antifouling nanofiltration. Recent Pat Nanotechnol 2016; 10(3): 189-201.
[http://dx.doi.org/10.2174/1872210510666160429145704] [PMID: 27136927]
[90]
Kamal T, Anwar Y, Khan SB, Chani MTS, Asiri AM. Dye adsorption and bactericidal properties of TiO2/chitosan coating layer. Carbohydr Polym 2016; 148: 153-60.
[http://dx.doi.org/10.1016/j.carbpol.2016.04.042] [PMID: 27185126]
[91]
Kamal T, Khan SB, Asiri AM. Synthesis of zero-valent Cu nanoparticles in the chitosan coating layer on cellulose microfibers: evaluation of azo dyes catalytic reduction. Cellulose 2016; 23: 1911-23.
[http://dx.doi.org/10.1007/s10570-016-0919-9]
[92]
Kamal T, Khan SB, Asiri AM. Nickel nanoparticles-chitosan composite coated cellulose filter paper: an efficient and easily recoverable dip-catalyst for pollutants degradation. Environ Pollut 2016; 218: 625-33.
[http://dx.doi.org/10.1016/j.envpol.2016.07.046] [PMID: 27481647]
[93]
Kamal T, Khan SB, Haider S, Alghamdi YG, Asiri AM. Thin layer chitosan-coated cellulose filter paper as substrate for immobilization of catalytic cobalt nanoparticles Int J Biol Macromol 2017; 104(Pt A): 56-62.
[http://dx.doi.org/10.1016/j.ijbiomac.2017.05.157] [PMID: 28571736]
[94]
Kamal T, Ul-Islam M, Khan SB, Asiri AM. Adsorption and photocatalyst assisted dye removal and bactericidal performance of ZnO/chitosan coating layer. Int J Biol Macromol 2015; 81: 584-90.
[http://dx.doi.org/10.1016/j.ijbiomac.2015.08.060] [PMID: 26321421]
[95]
Khan FU. Asimullah , Khan SB, et al. Novel combination of zero-valent Cu and Ag nanoparticles @ cellulose acetate nanocomposite for the reduction of 4-nitro phenol. Int J Biol Macromol 2017; 102: 868-77.
[http://dx.doi.org/10.1016/j.ijbiomac.2017.04.062] [PMID: 28428128]
[96]
Khan MSJ, Kamal T, Ali F, Asiri AM, Khan SB. Chitosan-coated polyurethane sponge supported metal nanoparticles for catalytic reduction of organic pollutants. Int J Biol Macromol 2019; 132: 772-83.
[http://dx.doi.org/10.1016/j.ijbiomac.2019.03.205] [PMID: 30928377]
[97]
Khan SA, Khan SB, Kamal T, Yasir M, Asiri AM. Antibacterial nanocomposites based on chitosan/Co-MCM as a selective and efficient adsorbent for organic dyes. Int J Biol Macromol 2016; 91: 744-51.
[http://dx.doi.org/10.1016/j.ijbiomac.2016.06.018] [PMID: 27287771]
[98]
Khan SB, Ali F, Kamal T, Anwar Y, Asiri AM, Seo J. CuO embedded chitosan spheres as antibacterial adsorbent for dyes. Int J Biol Macromol 2016; 88: 113-9.
[http://dx.doi.org/10.1016/j.ijbiomac.2016.03.026] [PMID: 26993528]
[99]
Khan SB, Khan SA, Marwani HM, et al. Anti-bacterial PES-cellulose composite spheres: dual character toward extraction and catalytic reduction of nitrophenol. RSC Advances 2016; 6: 110077-90.
[http://dx.doi.org/10.1039/C6RA21626A]
[100]
Pervaiz M, Ahmad I, Yousaf M, et al. Synthesis, spectral and antimicrobial studies of amino acid derivative Schiff base metal (Co, Mn, Cu, and Cd) complexes. Spectrochim Acta A Mol Biomol Spectrosc 2019; 206: 642-9.
[101]
Ul-Islam M, Wajid Ullah M, Khan S, et al. Recent advancement in cellulose based nanocomposite for addressing environmental challenges. Recent Pat Nanotechnol 2016; 10(3): 169-80.
[http://dx.doi.org/10.2174/1872210510666160429144916] [PMID: 27136931]
[102]
Zaman AU, Ahmad I, Pervaiz M, et al. A novel synthetic approach for the synthesis of pyrano 3,2-c quinolone-3carbaldehydes by using modified Vilsmeier Haack reaction, as potent antimicrobial agents. J Mol Struct 2019; 1180: 227-36.
[http://dx.doi.org/10.1016/j.molstruc.2018.11.030]
[103]
Ahmad I, Khan SB, Kamal T, Asiri AM. Visible light activated degradation of organic pollutants using zinc-iron selenide. J Mol Liq 2017; 229: 429-35.
[http://dx.doi.org/10.1016/j.molliq.2016.12.061]
[104]
Ali N, Ismail M, Khan A, Khan H, Haider S, Kamal T. Spectrophotometric methods for the determination of urea in real samples using silver nanoparticles by standard addition and 2nd order derivative methods. Spectrochim Acta A Mol Biomol Spectrosc 2018; 189: 110-5.
[105]
Chani MTS, Karimov KS, Khan SB, Kamal T, Asiri AM. Synthesis and pressure sensing properties of pristine zinc oxide nanopowder and its blend with carbon nanotubes. Curr Nanosci 2016; 12: 586-91.
[http://dx.doi.org/10.2174/1573413712666160502123744]
[106]
Kamal T. High performance NiO decorated graphene as a potential H-2 gas sensor. J Alloys Compd 2017; 729: 1058-63.
[http://dx.doi.org/10.1016/j.jallcom.2017.09.124]
[107]
Kavitha T, Kumar S, Prasad V, Asiri AM, Kamal T, Ul-Islam M. NiO powder synthesized through nickel metal complex degradation for water treatment. Desalination Water Treat 2019; 155: 216-24.
[http://dx.doi.org/10.5004/dwt.2019.24054]
[108]
Luo X, Zhan Y, Huang Y, Yang L, Tu X, Luo S. Removal of water-soluble acid dyes from water environment using a novel magnetic molecularly imprinted polymer. J Hazard Mater 2011; 187(1-3): 274-82.
[http://dx.doi.org/10.1016/j.jhazmat.2011.01.009] [PMID: 21269767]
[109]
Gao R, Kong X, Su F, He X, Chen L, Zhang Y. Synthesis and evaluation of molecularly imprinted core-shell carbon nanotubes for the determination of triclosan in environmental water samples. J Chromatogr A 2010; 1217(52): 8095-102.
[http://dx.doi.org/10.1016/j.chroma.2010.10.121] [PMID: 21093867]